Biomedical subjects

M Grioni

Publications and source records attributed to M Grioni.

At least 19 recordsLinked to original sources

PubMed2005

Localized electronic excitations in NiO studied with resonant inelastic X-Ray scattering at the Ni M threshold: evidence of spin flip.

We studied the neutral electronic excitations of NiO localized at the Ni sites by measuring the resonant inelastic x-ray scattering (RIXS) spectra at the Ni M2,3 edges. The good energy resolution allows an unambiguous identification of several spectral features due to excitations. The dependence of the RIXS spectra on the excitation energy gives evidence of local spin flip and yields a value of 125 +/- 15 meV for the antiferromagnetic exchange interaction. Accurate crystal field parameters are also obtained.

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PubMed2004

Low energy electronic excitations in the layered cuprates studied by copper L3 resonant inelastic x-ray scattering.

We have measured the resonant inelastic x-ray scattering (RIXS) spectra at the Cu L3 edge in a variety of cuprates. Exploiting a considerably improved energy resolution (0.8 eV) we recorded significant dependencies on the sample composition and orientation, on the scattering geometry, and on the incident photon polarization. The RIXS final states correspond to two families of electronic excitations, having local (dd excitations) and nonlocal (charge-transfer) character. The dd energy splitting can be estimated with a simple crystal field model. The RIXS at the L3 edge demonstrates here a great potential, thanks to the resonance strength and to the large 2p spin-orbit splitting.

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PubMed2003

Spectroscopic signatures of a bandwidth-controlled Mott transition at the surface of 1T-TaSe2.

High-resolution angle-resolved photoemission data show that a metal-insulator Mott transition occurs at the surface of the quasi-two-dimensional compound 1T-TaSe2. The transition is driven by the narrowing of the Ta 5d band induced by a temperature-dependent modulation of the atomic positions. A dynamical mean-field theory calculation of the spectral function of the half-filled Hubbard model captures the main qualitative feature of the data, namely, the rapid transfer of spectral weight from the observed quasiparticle peak at the Fermi surface to the Hubbard bands, as the correlation gap opens up.

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PubMed2002

Extremely small energy gap in the quasi-one-dimensional conducting chain compound SrNbO3.41.

Resistivity, optical, and angle-resolved photoemission experiments reveal unusual one-dimensional electronic properties of highly anisotropic SrNbO3.41. Along the conducting chain direction, we find an extremely small energy gap of only a few meV at the Fermi level. A discussion in terms of typical 1D instabilities (Peierls, Mott-Hubbard) shows that neither seems to provide a satisfactory explanation for the unique properties of SrNbO3.41.

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PubMed2002

New spectroscopy solves an old puzzle: the Kondo scale in heavy fermions.

Resonant inelastic x-ray scattering (RIXS) yields clear evidence of spectroscopic Kondo scales in heavy fermions. In YbInCu4 and YbAgCu4 RIXS probes the Yb2+ component of the hybrid ground state and the temperature dependence of the Yb 4f occupation. We report a sudden valence change at a phase transition in YbInCu4, but a continuous temperature dependence in YbAgCu4, consistent with the predictions of the Anderson impurity model, for a Kondo temperature T(K) = 70 K. These results solve a long-standing controversy and establish RIXS as a quantitative probe of the electronic structure of strongly correlated electron systems.

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PubMed2001

Spectroscopic indications of polaronic carriers in the quasi-one-dimensional conductor (TaSe4)2I.

Angle-resolved photoemission (ARPES) on the quasi-one-dimensional conductor (TaSe4)2I shows a hidden Fermi-surface crossing in its metallic state and the opening of a Peierls gap at low temperatures. The underlying quasiparticles have vanishing spectral weight and extremely short coherence lengths. They are interpreted as polarons in the strong-coupling adiabatic limit, and almost all their ARPES weight is incoherent. These observations suggest a scenario where the long-standing contradictions between ARPES and other experiments on Peierls materials could be resolved.

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PubMed2000

Electronic structure of solids with competing periodic potentials.

When electrons are subject to a potential with two incommensurate periods, translational invariance is lost, and no periodic band structure is expected. However, model calculations based on nearly free one-dimensional electrons and experimental results from high-resolution photoemission spectroscopy on a quasi-one-dimensional material do show dispersing band states with signatures of both periodicities. Apparent band structures are generated by the nonuniform distribution of electronic spectral weight over the complex eigenvalue spectrum.

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PubMed2000

Dynamical properties of the one-dimensional band insulator (NbSe4)3I

Optical and photoemission experiments reveal unexpected spectral signatures of one-dimensional band insulators. In the model compound (NbSe (4))3I the optical conductivity decays as a power law sigma(1)(omega) approximately omega(-4.25) above a sharp gap edge. Photoemission observes both the valence and a shadow band, produced by a commensurate superstructure. We identify an optical and photoemission band gap consistent with other measurements but much smaller than the energy scale defined by the dispersion of the band peak in the photoemission spectra.

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PubMed1996