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M Knupfer

Publications and source records attributed to M Knupfer.

At least 19 recordsLinked to original sources
PubMed2006

Stripe correlations in Na(0.75)CoO2.

We present a combined high-energy x-ray diffraction and local-density approximation study of the sodium ordering in Na(0.75)CoO2. The obtained results rule out previously proposed Na-ordering models and provide strong evidence for the formation of sodium-density stripes in this material. The local-density approximation calculations prove that the sodium-density stripes lead to a sizable dip in the density of the Co states at the Fermi level, pointing to band structure effects as a driving force for the stripe formation. This indicates that the sodium ordering is connected to stripelike charge correlations within the CoO2 layers, leading to an astonishing similarity between the doped cuprates and the NaxCoO2 compounds.

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PubMed2006

Constituents of the quasiparticle spectrum along the nodal direction of high-Tc cuprates.

Applying the Kramers-Kronig consistent procedure, developed earlier, we investigate in detail the formation of the quasiparticle spectrum along the nodal direction of high-Tc cuprates. The heavily discussed "70 meV kink" on the renormalized dispersion exhibits a strong temperature and doping dependence when purified from structural effects such as bilayer splitting, diffraction replicas, etc. This dependence is well understood in terms of fermionic and bosonic constituents of the self-energy. The latter follows the evolution of the spin-fluctuation spectrum, emerging below some doping dependent temperature and sharpening below Tc, and is mainly responsible for the formation of the kink in question.

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PubMed2006

Kinks, nodal bilayer splitting, and interband scattering in YBa2Cu3O(6+x).

We apply the new-generation angle-resolved photoemission spectroscopy methodology to the most widely studied cuprate superconductor YBa2Cu3O(6+x). Considering the nodal direction, we found noticeable renormalization effects known as kinks both in the quasiparticle dispersion and scattering rate, the bilayer splitting, and evidence for strong interband scattering--all the characteristic features of the nodal quasiparticles detected earlier in Bi2Sr2CaCu2O(8+delta). The typical energy scale and the doping dependence of the kinks clearly point to their intimate relation with the spin-1 resonance seen in the neutron scattering experiments. Our findings strongly suggest a universality of the electron dynamics in the bilayer superconducting cuprates and a dominating role of the spin fluctuations in the formation of the quasiparticles along the nodal direction.

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PubMed2006

Parity of the pairing bosons in a high-temperature Pb-Bi2Sr2CaCu2O8 bilayer superconductor by angle-resolved photoemission spectroscopy.

We report the observation of a novel effect in the bilayer Pb-Bi2Sr2CaCu2O8 (Pb-Bi2212) high-T(c) superconductor by means of angle-resolved photoemission with circularly polarized excitation. Different scattering rates, determined as a function of energy separately for the bonding and antibonding copper-oxygen bands, strongly imply that the dominating scattering channel is odd with respect to layer exchange within a bilayer. This is inconsistent with a phonon-mediated scattering and favors the participation of the odd collective spin excitations in the scattering mechanism in near-nodal regions of the k space, suggesting a magnetic nature of the pairing mediator.

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PubMed2006

Effect of Zn and Ni impurities on the quasiparticle renormalization of superconducting Bi-2212.

The Cu substitution by Zn and Ni impurities and its influence on the mass renormalization effects in angle-resolved photoelectron spectra (ARPES) of Bi2Sr2CaCu2O8-delta is addressed. We show that the nonmagnetic Zn atoms have a much stronger effect in both the nodal and antinodal parts of the Brillouin zone than magnetic Ni. The observed changes are consistent with the behavior of the spin resonance mode as seen by inelastic neutron scattering in YBCO. This strongly suggests that the "peak-dip-hump" and the kink in ARPES on the one side and neutron resonance on the other are closely related features.

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PubMed2005

Tetra-t-butyl magnesium phthalocyanine on gold: electronic structure and molecular orientation.

In this work we have investigated the electronic structure and the molecular orientation of (t-Bu)(4)PcMg (tetra-t-butyl magnesium phthalocyanine) on polycrystalline and single crystalline gold substrates using photoemission spectroscopy and x-ray absorption spectroscopy, and we compare the results to the unsubstituted PcCu (copper phthalocyanine). The C 1s photoemission spectrum is described similar to unsubstituted relatives with an additional component for the aliphatic substituents. The variation of the excitation energy causes distinct differences in the shape of the C 1s spectrum, which is very useful for the analysis of the molecular orientation in the uppermost layer. It is shown that despite of the sterically demanding substituents, ordered sublimed films of (t-Bu)(4)PcMg are accessible, the orientation of the molecules, however, is different from the orientation of the unsubstituted relatives.

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PubMed2004

Transition from a Tomonaga-Luttinger liquid to a fermi liquid in potassium-intercalated bundles of single-wall carbon nanotubes.

We report on the first direct observation of a transition from a Tomonaga-Luttinger liquid to a Fermi-liquid behavior in potassium-intercalated mats of single-wall carbon nanotubes. Using high resolution photoemission spectroscopy, an analysis of the spectral shape near the Fermi level reveals a Tomonaga-Luttinger liquid power law scaling in the density of states for the pristine sample and for low dopant concentration. As soon as the doping is high enough to achieve a filling of the conduction bands of the semiconducting tubes, a distinct transition to metallic single-wall carbon nanotube bundles with the scaling behavior of a normal Fermi liquid occurs.

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PubMed2004

Manifestation of the magnetic resonance mode in the nodal quasiparticle lifetime of the superconducting cuprates.

Studying the nodal quasiparticles in superconducting cuprates by photoemission with highly improved momentum resolution, we show that a new "kink" feature in the scattering rate is a key to uncover the nature of electron correlations in these compounds. Our data provide evidence that the main doping independent contribution to the scattering can be well understood in terms of the conventional Fermi liquid model, while the additional doping dependent contribution has a magnetic origin. This sheds doubt on applicability of a phonon-mediated pairing mechanism to high-temperature superconductors.

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PubMed2004

Circular dichroism in angle-resolved photoemission spectra of under- and overdoped Pb-Bi2212.

We use angle-resolved photoemission with circularly polarized excitation to demonstrate that in the 5 x 1 superstructure-free (Pb,Bi)(2)Sr(2)CaCu(2)O(8+delta) (Pb-Bi2212) material there are no signatures of time-reversal symmetry breaking in the sense of the criteria developed earlier [Nature (London) 416, 610 (2002)]]. The dichroic signal retains reflection antisymmetry as a function of temperature and doping and in all mirror planes, precisely defined by the experimental dispersion at low energies. The obtained results demonstrate that the signatures of time-reversal symmetry violation in pristine Bi2212, as determined by angle-resolved photoemission spectroscopy, are not a universal feature of all cuprate superconductors.

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PubMed2003

Doping dependence of the mass enhancement in (Pb,Bi)2Sr2CaCu2O8 at the antinodal point in the superconducting and normal states.

Angle-resolved photoemission spectroscopy is used to study the mass renormalization of the charge carriers in the high-T(c) superconductor (Pb,Bi)2Sr2CaCu2O8 in the vicinity of the (pi,0) point in the superconducting and the normal states. Using matrix element effects at different photon energies and due to a high momentum and energy resolution the bonding and the antibonding bands could be separated in the whole dopant range. A huge coupling to a bosonic collective mode is observed below T(c) for both bands, in particular, for the underdoped case. Above T(c), a weaker coupling to a continuous spectrum of modes is detected.

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PubMed2003

Evidence for two types of low-energy charge transfer excitations in Sr2CuO3.

A comparative analysis of electron energy-loss spectroscopy (EELS) spectra for the 1D insulating cuprate Sr2CuO3 with transferred momentum q--> axially and radially to the chain axis allows one to elucidate the structure of the charge transfer gap in in-chain response. It is determined by the superposition of two types of excitations with different magnitudes of dispersion. The low-energy response with q--> radially to the chain direction, but yet within the plane of CuO4 plaquettes, exhibits also a dispersionless peak near 2 eV. The theoretical simulation of the EELS data using exact diagonalizations of an appropriate extended Hubbard Hamiltonian for relevant clusters requires the explicit consideration of low-lying oxygen 2p pi states within the CuO4 plaquette plane beyond the standard pd sigma extended Hubbard model widely used for cuprates with corner-shared CuO4 plaquettes.

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PubMed2003

Anomalous enhancement of the coupling to the magnetic resonance mode in underdoped Pb-Bi2212.

High-resolution angle-resolved photoemission with variable excitation energies is used to disentangle bilayer splitting effects and intrinsic (self-energy) effects in the electronic spectral function near the (pi,0) point of differently doped (Pb,Bi)(2)Sr(2)CaCu(2)O(8+delta). In contrast to overdoped samples, where intrinsic effects at the (pi,0) point are virtually absent, we find in underdoped samples intrinsic effects in the superconducting-state (pi,0) spectra of the antibonding band. This intrinsic effect is present only below the critical temperature and weakens considerably with doping. Our results give strong support for models which involve a strong coupling of electronic excitations with the resonance mode seen in inelastic neutron scattering experiments.

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PubMed2003

Infrared response of multiwalled boron nitride nanotubes.

We report the infrared (IR) response of bulk samples of multiwalled boron nitride nanotubes, produced by a substitution reaction from single walled carbon nanotubes, which is dominated by two characteristic BN-vibrations at 800 and 1372 cm-1.

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PubMed2002

Origin of the peak-dip-hump line shape in the superconducting-state (pi,0) photoemission spectra of Bi2Sr2CaCu2O8.

From detailed high-resolution measurements of the photon energy dependence of the (pi,0) superconducting-state photoemission spectrum of the bilayer Bi high-temperature superconductors, we show that the famous peak-dip-hump line shape is dominated by a superposition of spectral features originating from different electronic states which reside at different binding energies, but are each describable by essentially identical single-particle spectral functions. The previously identified bilayer-split CuO2 bands are the culprit: with the "superconducting" peak being due to the antibonding band, while the hump is mainly formed by its bonding bilayer-split counterpart.

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PubMed2002

Anisotropy and interplane interactions in the dielectric response of graphite.

We determined the anisotropic dielectric response of graphite by means of time-dependent density-functional theory and high-resolution valence electron energy-loss spectroscopy. The calculated loss function was in very good agreement with the experiment for a wide range of momentum-transfer orientations with respect to the graphitic basal planes, provided that local-field effects were included in the response. The calculations also showed strong effects of the interlayer Coulomb interaction on the total pi+sigma plasmon. This finding must be taken into account for the explanation of recent loss spectra of carbon nanotube materials.

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PubMed2000

Joys and pitfalls of fermi surface mapping in Bi(2)Sr(2)CaCu(2)O(8+delta) using angle resolved photoemission

On the basis of angle-scanned photoemission data recorded using unpolarized radiation, with high (E,k) resolution, and an extremely dense sampling of k space, we resolve the current controversy regarding the normal state Fermi surface (FS) in Bi(2)Sr(2)CaCu(2)O(8+delta). The true picture is simple, self-consistent, and robust: the FS is holelike, with the form of rounded tubes centered on the corners of the Brillouin zone. Two further types of features are also clearly observed: shadow FSs, which are most likely to be due to short range antiferromagnetic spin correlations, and diffraction replicas of the main FS caused by passage of the photoelectrons through the modulated Bi-O planes.

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