PubMed Health⌕ Search

Biomedical subjects

M Korolczuk

Publications and source records attributed to M Korolczuk.

4 recordsLinked to original sources
PubMed2000

How faster and cheaper to determine chromium by adsorptive cathodic stripping voltammetry in the presence of DTPA and nitrate.

A modification of the voltammetric procedure for the determination of chromium in the presence of DTPA and nitrates was proposed. Morpholinoethanesulfonic (MES) acid and its sodium salt were used for stabilisation of pH instead of acetate buffer. In the presence of MES the determination of chromium can be carried out in the presence of dissolved oxygen without decrease of sensitivity of the measurements. Elimination of the purge step decreases total analysis time and saves gas.

Journal Article↗
PubMed1996

Selective method for the determination of gold by anodic stripping voltammetry.

A highly selective method for the deter- mination of gold by anodic stripping voltammetry is described. For preconcentration a glassy carbon electrode, activated by deposition of small amounts of gold before the measurement, is proposed. The Au(3+) reduction process at such an electrode is effective starting with the potential +0.4 V vs. Ag/AgCl electrode. A linear dependence of the current of the gold stripping peak on the gold concentration was obtained in the range from 5x10(-8) to 1x10(-6) mol/l. The relative standard deviation for 2x10(-7) mol/l HAuCl(4) was 4.2% (n=5). The detection limit was 4x10(-9) mol/l. The accuracy of the method was verified by the determination of gold in reference materials.

Journal Article↗
PubMed1990

[Study on the content of certain elements in retained teeth].

The content of calcium, phosphorus.potassium and zinc was determined in 21 retained canine teeth and in a control group of canine teeth erupted completely. In the measurement the method of X-ray fluorescence was used. The obtained results were subjected to statistical analysis. In relation to control canines the retained teeth contained significantly more calcium and phosphorus and significantly less potassium. No significant differences were found in zinc content.

Calcium↗