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M M Banaszak Holl

Publications and source records attributed to M M Banaszak Holl.

4 recordsLinked to original sources
PubMed2004

Monolayer pattern evolution via substrate strain-mediated spinodal decomposition.

Investigations of octylsilane (C8H17SiH3) monolayer pattern formation on Au(111) are reported. Scanning tunneling microscopy data display the evolution of a approximately 6 nm scale pattern of interwoven features concomitant with ejection of surface Au atoms and relaxation of the Au(111) 23xsqrt[3] surface reconstruction. Numerical simulations suggest the surface dynamics are governed by a substrate strain-mediated spinodal decomposition mechanism, novel to organic monolayer formation. Collectively, the experimental and theoretical data indicate strain-inducing Si-Au bond interactions drive the pattern formation and the alkyl chains play a negligible role.

Journal Article↗
PubMed2004

Deformability of poly(amidoamine) dendrimers.

Experimental data indicates that poly(amidoamine) (PAMAM) dendrimers flatten when in contact with a substrate, i.e. they are no longer spherical, but resemble flat disks. In order to better understand the deformation behavior of these branched polymers, a series of atomistic molecular dynamics simulations is performed. The resulting flattened dendrimer conformations are compared to atomic force microscopy (AFM) images of individual dendrimers at air/mica and water/mica interfaces. The ability of the polymers to deform is investigated as a function of dendrimer generation (2-5) and the required energies are calculated. Our modeling results show good agreement with the experimental AFM images, namely that dendrimers are highly flexible and capable of forming multiple interaction sites between most of their branch ends and the substrate. The deformation energy scales with dendrimer generation and does not indicate an increase in stiffness between generations 2 and 5 due to steric effects.

Biocompatible Materials↗
PubMed2000

Determination of spherosiloxane cluster bonding to Si(100)-2 x 1 by scanning tunneling microscopy.

Scanning tunneling microscopy is used to determine the bonding geometry of the spherosiloxane cluster, H(8)Si(8)O(12) , on Si(100)-2 x 1. The images obtained are consistent with monovertex bonding to the Si(100)-2 x 1 surface via activation of a single Si-H bond. Filled and empty state images show good agreement with calculations of the electron density distribution of the cluster as well as the Psi(2) highest occupied molecular orbital and lowest unoccupied molecular orbital surface plots of the cluster.

Journal Article↗