M P Doherty | PubMed Health

PubMed2005

Time-dependent strength of colloidal gels.

Colloidal silica gels are shown to stiffen with time, as demonstrated by both dynamic light scattering and bulk rheological measurements. Their elastic moduli increase as a power law with time, independent of particle volume fraction; however, static light scattering indicates that there are no large-scale structural changes. We propose that increases in local elasticity arising from bonding between neighboring colloidal particles can account for the strengthening of the network, while preserving network structure.

Journal Article↗

PubMed2004

Limits to gelation in colloidal aggregation.

We show that the dynamics of large fractal colloid aggregates are well described by a combination of translational and rotational diffusion and internal elastic fluctuations, allowing both the aggregate size and internal elasticity to be determined by dynamic light scattering. The comparison of results obtained in microgravity and on Earth demonstrates that cluster growth is limited by gravity-induced restructuring. In the absence of gravity, thermal fluctuations ultimately inhibit fractal growth and set the fundamental limitation to the lowest volume fraction which will gel.

Colloids↗

PubMed1999

Are oblique views needed for trauma radiography of the distal extremities?

OBJECTIVE: To our knowledge, few studies exist on the importance of the oblique view when radiography of the distal extremities is performed after acute trauma. Our prospective study aimed to determine whether the oblique view uniquely revealed abnormalities or clarified findings when it was obtained along with routine frontal and lateral radiographs. SUBJECTS AND METHODS: We prospectively interpreted 1461 consecutive radiographic examinations of the distal extremities in patients presenting with acute trauma to four family medicine clinics. The anatomic sites radiographed included the ankle, foot, toe, wrist, hand, finger, and thumb. Each study was interpreted and given a diagnostic certainty score using the lateral and posteroanterior or anteroposterior views only and then scored again with the oblique view added. RESULTS: The examinations included 421 with abnormal findings, 34 with equivocal findings, and 1006 with normal findings. The addition of the oblique view changed the interpretation in 70 (4.8%) of the 1461 examinations. Of these changed interpretations, 39 were changed from equivocal to either positive or negative, three from positive to negative, and 28 from negative to positive. Addition of the oblique view increased diagnostic confidence: The percentage of examinations scored as having probably normal, equivocal, and probably abnormal findings decreased from 13.9% with two views to 8.4% with three views (p < .0001). The oblique view was equally valuable in the ankle, foot, toe, wrist, hand, finger, and thumb. CONCLUSION: In the distal extremities, the oblique view uniquely reveals abnormalities and increases the confidence of the final radiographic diagnosis when the oblique view is interpreted along with frontal and lateral radiographs.

Adolescent↗