Biomedical subjects

M Quesada-Pérez

Publications and source records attributed to M Quesada-Pérez.

8 recordsLinked to original sources

PubMed2006

Electric double layers with electrolyte mixtures: integral equations theories and simulations.

A study of a planar electric double layer (EDL) in the presence of mixtures of electrolyte is presented. In particular, results from the Hyper-Netted-Chain/Mean-Spherical-Approximation (HNC/MSA) theory are compared with Monte Carlo (MC) simulations. In this way, the charge inversion induced by mixtures of multivalent and monovalent counterions is probed. Since overcharging phenomena in nature emerge under such conditions, the role of ion-ion correlations in the EDL appears as a crucial point in this kind of study. Unlike previous related works, a realistic hydrated ion size is used in the HNC/MSA calculations and simulations. In this way, a qualitative agreement between the results obtained from the theory and MC simulations is found. However, some discrepancies arise when the charge inversion is expected to be more noticeable, namely at high surface charges and/or elevated concentrations of multivalent electrolytes. Such differences are explained in terms of an overestimation of the charge inversion by the integral equation (IE) formalism.

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PubMed2005

Simulation of electric double layers undergoing charge inversion: mixtures of mono- and multivalent ions.

In this paper, the electric double layer (EDL) of a charged plane in the presence of mixtures of 1:1 and 3:1 electrolytes has been investigated through Monte Carlo (MC) simulations using a nonrestrictive primitive model of EDL. In particular, the charge inversion in colloids (attributable to an accumulation of counterions on the surface) can be better understood by means of the simulations performed here. Moreover, two mechanisms proposed for charge inversion are probed: The formation of a strongly correlated layer (SCL) of multivalent counterions and excluded volume effects (to which we will also refer as ion size correlations). Our results are in agreement with the behavior found experimentally for some model colloids with increasing the concentration of monovalent salt in the presence of trivalent ions, which clearly supports the relevance of ion size correlations. In contrast, certain disagreement with predictions of SCL theories is reported.

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PubMed2004

Simulation of electric double layers with multivalent counterions: ion size effect.

In this paper, the structure of the electric double layer in the presence of (mostly) multivalent counterions is investigated through Monte Carlo simulations. Unlike previous similar studies addressing this matter, the difference of this study lies in the use of realistic hydrated ion sizes. Additionally, two different methods for calculating energies in the Metropolis algorithm are applied. The obtained results show that the conclusions of preceding papers must be revised. In particular, our simulations suggest the existence of certain ion layering effects at high surface charge densities, which are not accounted for by integral equation theories in the case of divalent counterions. These layering effects could justify why the overcharging phenomena due to ion size correlations are hardly observable in real colloids with divalent counterions. The existence of charge inversion due to ion size correlations (and without requiring specific counterion adsorption) is probed for trivalent counterions. Moreover, the hypernetted-chain/mean-spherical-approximation is tested under conditions not studied yet.

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PubMed2003

Effective charges of colloidal particles obtained from collective diffusion experiments.

In this work, the collective diffusion coefficient of highly charged colloidal particles in dilute dispersions has been measured by means of dynamic light scattering. The possibility of obtaining valuable information about the particle charge from these data is looked into with the help of electrophoresis experiments. Our results suggest that this is possible in the case of slight or moderately interacting particles as long as experimental data are properly treated. For highly interacting colloids, however, such information could not be so reliable, presumably due to certain shortcomings of the experimental technique at low angle. The role of charge renormalization is also discussed in this work.

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PubMed2002

Interaction potentials, structural ordering and effective charges in dispersions of charged colloidal particles.

As colloidal dispersions of charged particles exhibit a wide variety of commercial, technological and scientific applications, a considerable theoretical effort has been devoted to finding an effective interaction potential from primitive models. The forces derived from this potential should justify the spatial ordering experimentally observed under certain conditions. This paper reviews the advances in these theoretical studies as well as some experiments (based on the mentioned order) that try to corroborate them. Special attention has been paid to the Derjaguin-Landau-Verwey-Overbeek (DLVO) potential. Nowadays, many of these theoretical investigations suggest that it could be applied if some of its parameters are renormalized. Nevertheless, to achieve a renormalization procedure in a strict way (from a primitive model) is a difficult task as a result of the size and charge asymmetries between small ions and macroions. Thus, several procedures for computing renormalized charges in a simple way have been developed. However, the notion of effective charge has also been widely used (as a adjustable parameter) in order to justify results found for several kinds of colloids (like solid particle dispersions or micellar systems) by means of quite different experimental techniques. Renormalization (as well as ion condensation) approaches, experiments and the controversial relationship between theoretical and phenomenological effective charges are also reviewed in this work.

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PubMed2001

An Experimental Test of the Ion Condensation Theory for Spherical Colloidal Particles.

This paper deals with the notion of ion condensation for spherical colloids and, more specifically, with a recent model developed to predict effective charges (Y. Levin, M. C. Barbosa, and M. N. Tamashiro, Europhys. Lett. 41, 123, 1998). Electrophoretic mobility measurements (carried out for a set of well-characterized latexes) were used to find out to what extent this theory is able to accounts for: (i) the insensitivity of mobility to surface charge, and (ii) the small values of electrokinetic charge found at low ionic strength. As the Levin theory was developed assuming no added salt, a previous discussion about the effect of additional electrolyte was needed. Contrary to what other authors have reported, our results do not support the above-mentioned theory. Copyright 2001 Academic Press.

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PubMed1999

Probing Electrostatic Forces in Colloidal Suspensions through Turbidity Data.

This paper deals with the use of turbidimetry to obtain information on forces between negatively charged polymeric particles at very low ionic strength. The specific turbidity of deionized colloidal suspensions is measured and compared with the values obtained for suspensions of noninteracting particles. From these data, the integrated structure factors are experimentally obtained for several latex samples. These functions are fitted using the repulsive part of the DLVO potential, the Ornstein-Zernike equation, and the hyper-netted chain closure, which enables us to interpret the results in terms of an effective charge. The reliability of these values is discussed. In addition, a comparison between turbidimetry and light scattering data is presented. Copyright 1999 Academic Press.

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PubMed1998

Effective Charge on Polymer Colloids Obtained Using a Renormalization Model.

Static light scattering has been used to study the electrostatic interaction between colloidal particles. Experiments were carried out using a latex with a very small diameter, allowing structure determination at high particle concentration. The obtained effective charge characterizing this interaction is found to be smaller than the bare charge determined from titration. A renormalization model connecting both values has been used. The agreement between the renormalized charge and that obtained from scattering data seems to point out that this model operates well. Copyright 1998 Academic Press.

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