Redox-Switched Control of Binding Strength in Hydrogen-Bonded Metallocene Complexes.
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Biomedical subjects
MB Hursthouse
Publications and source records attributed to MB Hursthouse.
A New, Simple Route to Novel Gold Clusters: Structure of an Au(6)Ag Wheel with a Gold Rim This research was supported by the Dirección General de Enseñanza Superior (PB 98-0542) and the Engineering and Physical Sciences Research Council.
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2-(2-pyridylimino)-2H-1,2,4-thiadiazolo
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fac,trans-
The crystal structure of the heterobimetallic title compound, [ReRuCl(C(10)H(16)As(2))(2)(C(10)H(8)N(2))(2)(CO)(3)](PF(6))(2). 2C(3)H(6)O, is described. Both metal centres have pseudo-octahedral coordination geometries, with a facial arrangement of the carbonyl ligands at Re(I) and a trans disposition of the diarsine ligands at Ru(II). The dihedral angle between the pyridyl rings of the 4, 4'-bipyridine bridging ligand is 13.9 (6) degrees.
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trans-4-
The crystal structure of the dipolar chromophoric title compound, C(20)H(20)N(3)(+).PF(6)(-), is described. The phenylene and pyridyl rings are almost coplanar [dihedral angle 7.5 (2) degrees ], but the phenyl substituent forms a dihedral angle of 56.6 (1) degrees with the pyridyl ring. The compound crystallizes in the non-centrosymmetric space group Cc and is a likely candidate for the display of quadratic non-linear optical effects.
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