Biomedical subjects
Publications and source records attributed to ME Michel-Beyerle.
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We have been able to determine the occupancy of the quinone site at the A-branch (Q(A)) of a reaction center preparation with an accuracy of 2%. This is achieved by accumulating the P(+)Q(-)(A) state after multiple actinic excitation and monitoring the extent of the 30 ms ground state bleaching. This bleaching is corrected for deviations from complete saturation due to competing charge separation to the B-branch. On the other hand, knowledge of the Q(A) content is indispensable for determining the yield of B-branch charge separation from nanosecond transients associated with the recombination of P(+)H(-)(B), which have to be corrected for the nanosecond signal originating from P(+)H(-)(A) of RCs having lost Q(A).
The recombination dynamics of a transition metal redox system monitored by femtosecond pump-probe spectroscopy are shown to be sensitive to high magnetic fields at times shorter than 10 picoseconds. The effect, based on coherent population beats of different spin states, is quantitatively accounted for and allows direct access to spin relaxation rates far beyond the time resolution of the fastest electron paramagnetic resonance technique. The presence of this ultrafast magnetic field effect helps in understanding complex reaction schemes in transition metal chemistry, which occur in a wide range of fields, such as bioinorganic chemistry and catalysis.