Biomedical subjects
Publications and source records attributed to Martin Bröring.
Di(p-tolyl)diazomethane reacts with the tripyrrinate TrpyPdOAc(F) 1 after activation with NaBAr(F) to yield the first stable Pd(II) complex 2 of a non-Arduengo type carbene ligand, which could be characterised by X-ray crystallography.
The treatment of the strained complex TrpyPdOAc(F) 1 with NaBAr(F), followed by the addition of trimethylphosphine, yields the stable cationic 16VE- or 18VE-complexes 3 and 4, depending on the amount of phosphane added.
The metalation reactions of the 2,2'-bidipyrrin 4 with different rhodium(I) precursors yield the complexes 5 and 6 and the unusual corrinoid 7, depending only on the type of the ancillary ligand employed.
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