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Michael Hilgendorff

Publications and source records attributed to Michael Hilgendorff.

3 recordsLinked to original sources

Quantum dot modified multiwall carbon nanotubes.

A novel strategy for the fabrication of multiwall carbon nanotube-nanocrystal heterostructures is shown. Different quantum dots (QDs) with narrow size distributions were covalently coupled to carbon nanotubes (CNTs) and silica-coated CNTs in a simple, uniform, and controllable manner. The structural and optical properties of CNT/QD heterostructures are characterized by electron microscopy and photoluminescence spectroscopy. Complete quenching of the PL bands in both QD core and core/shell heterostructures was observed after adsorption to the CNTs, presumably through either carrier ionization or energy transfer. The deposition of a silica shell around the CNTs preserves the fluorescence properties by insulating the QD from the surface of the CNT.

Journal Article↗

From colloidal Co/CoO core/shell nanoparticles to arrays of metallic nanomagnets: surface modification and magnetic properties.

The magnetic properties of nanoparticles can be subject to strong variations as the chemical composition of the particle surface is modified. To study this interrelation of surface chemistry and magnetism, self-assembled layers of colloidal 9.5 nm Co/CoO core/shell nanoparticles were exposed to mild reactive hydrogen and oxygen plasmas. The consecutive oxygen/hydrogen plasma treatment transforms the particle layer into an array of metallic nanomagnets with complete reduction of the oxide and removal of the organic surfactants. The original arrangement of the particle array and the number of Co atoms per particle remains unchanged within the experimental error, and thus this is a possible route for the fabrication of ultrahigh-density magnetic bit structures from colloidal dispersions. The magnetic properties can be tuned by controlling the thickness of the surface oxide layer, which magnetically hardens the particles, as evidenced by element-specific magnetic hysteresis loops.

Journal Article↗

Electrochemistry of a carbon microfiber adsorbed by cobalt nanoparticles.

The adsorption of cobalt nanoparticles on a carbon microfiber surface has been electrochemicaly detected. The redox processes observed in an electrochemical cell filled with redistilled water and equipped with the carbon fiber microelectrode modified by cobalt nanoparticles have been compared to those observed in an aqueous solution of Co2+ cations. The movement of the adsorbed nanoparticles has been demonstrated by the feedback capacitance-potential method.

Adsorption↗