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Mihaela Ungureanu

Publications and source records attributed to Mihaela Ungureanu.

2 recordsLinked to original sources

Basic aspects concerning the event-synchronous interference canceller.

The adaptive noise canceller (ANC) is a commonly used linear system method for noise reduction in cases where the disturbing noise can be separately recorded (reference signal) and is not correlated with the signal of interest. In case of a periodic disturbing signal, special solutions are described in literature. Problems, however, arise when the propagation of the noise from the source to the recording sensors passes nonlinear structures. An ANC modification proposed for this case by Strobach et al. and applied by several other researchers, thus, uses an artificial reference signal, based on event triggered averaging of segments of the recorded wanted (but disturbed) signal in order to obtain a template for the repetitive distortion sequence and to construct the artificial reference signal. The effect of the averaging and the error introduced by this approximation of the real disturbing signal was not addressed in literature until now, thus, this paper presents some basic theoretical considerations on this topic. Methods are demonstrated in simulations and real biosignal processing, and application aspects are discussed.

Algorithms↗

Thermically and electrochemically induced isomerization of a (bis(ferrocene)-cyclam)copper(II) complex.

The new bis(ferrocene)-cyclam macrocycle 1,8-bis(ferrocenylmethyl)-1,4,8,11-tetraazacyclotetradecane, denoted L, has been synthesized. Two Cu(II) complexes with L have been isolated and characterized from X-ray structure determination and electrochemical studies. These two LCu(II) complexes correspond to the type I (ferrocenyl subunits in the same side of the cyclam plane) and type III (ferrocenyl subunits above and below the cyclam plane) isomers. The type I LCu(II) complex was synthesized from L and a Cu(2+) salt, while the type III isomer was obtained by oxidation in air or by comproportionation of the Cu(I) complex. The interconversion between type I and type III LCu(II) complexes is negligible in acetonitrile and slow in dimethyl sulfoxide but fast via an electrochemical reduction-reoxidation cycle. According to UV-vis and electrochemical characterizations, the type III isomer is thermodynamically more stable and the type I isomer is kinetically favored. A type III LNi(II) complex was also isolated and characterized by X-ray diffraction analysis and from electrochemical studies.

Journal Article↗