Crystal structure of 3,4,6,7,15,16,17,18,19,20,21,27-dodecahydro-2,5,8-trioxa-16,20-diazatetracyclo[20.4.1.(16,20)0.0(9,14)]heptacosa-9,11,13,22,24,26(1)-hexaene.
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Biomedical subjects
N Akduran
Publications and source records attributed to N Akduran.
Crystal structure of 3,4,6,7,15,16,17,18,19,20,21-undecahydro-2,5,6-trioxa-16,20- diazatricyclo[20.4.0.0(9,14)]hexacosa-9,11,13,22,24,26(1)-hexaene.
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N-[Bis(2,4,6-trimethylphenoxy)phosphinoyl]-P,P,P-tris(2,4, 6-trimethylphenoxy)phosphazene.
The title compound, C(45)H(55)NO(6)P(2), consists of an acyclic P=N-P(O) monophosphazene chain and five bulky 2,4,6-trimethylphenoxy side groups which predominantly determine the molecular shape. Although the P-N single [1.586 (3) A] and P=N double [1.517 (3) A] bonds are significantly different from each other, both are substantially shorter than the ideal P-N single bond. The P-N-P angle [146.0 (2) degrees ] corresponds to the upper limit reported for acyclic phosphazene derivatives in the literature.
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