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N D Mathur

Publications and source records attributed to N D Mathur.

4 recordsLinked to original sources

Multiferroic and magnetoelectric materials.

A ferroelectric crystal exhibits a stable and switchable electrical polarization that is manifested in the form of cooperative atomic displacements. A ferromagnetic crystal exhibits a stable and switchable magnetization that arises through the quantum mechanical phenomenon of exchange. There are very few 'multiferroic' materials that exhibit both of these properties, but the 'magnetoelectric' coupling of magnetic and electrical properties is a more general and widespread phenomenon. Although work in this area can be traced back to pioneering research in the 1950s and 1960s, there has been a recent resurgence of interest driven by long-term technological aspirations.

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Giant electrocaloric effect in thin-film PbZr(0.95)Ti(0.05)O3.

An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. We demonstrate a giant electrocaloric effect (0.48 kelvin per volt) in 350-nanometer PbZr(0.95)Ti(0.05)O3 films near the ferroelectric Curie temperature of 222 degrees C. A large electrocaloric effect may find application in electrical refrigeration.

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Weak charge-lattice coupling requires reinterpretation of stripes of charge order in La1-xCaxMnO3.

Modulations in manganites attributed to stripes of charge/orbital/spin order are thought to result from strong electron-lattice interactions that lock the superlattice and parent lattice periodicities. Surprisingly in La1-xCaxMnO3 (x>0.5,90 K), convergent beam (3.6 nm spot) electron diffraction patterns rule out charge stacking faults and indicate a superlattice with uniform periodicity. Moreover, large area electron diffraction peaks are sharper than simulations with stacking faults. Since the electron-lattice coupling does not lock the two periodicities (to yield stripes) it may be too weak to strongly localize charge.

Journal Article↗