PubMed Health⌕ Search

Biomedical subjects

N P Ong

Publications and source records attributed to N P Ong.

16 recordsLinked to original sources
PubMed2006

Large enhancement of the thermopower in Na(x)CoO2 at high Na doping.

Research on the oxide perovskites has uncovered electronic properties that are strikingly enhanced compared with those in conventional metals. Examples are the high critical temperatures of the cuprate superconductors and the colossal magnetoresistance in the manganites. The conducting layered cobaltate Na(x)CoO2 exhibits several interesting electronic phases as the Na content x is varied, including water-induced superconductivity and an insulating state that is destroyed by field. Initial measurements showed that, in the as-grown composition, Na(x)CoO2 has moderately large thermopower S and conductivity sigma. However, the prospects for thermoelectric cooling applications faded when the figure of merit Z was found to be small at this composition (0.6 0.75, S undergoes an even steeper enhancement. At the critical doping x(p) approximately 0.85, Z (at 80 K) reaches values approximately 40 times larger than in the as-grown crystals. We discuss prospects for low-temperature thermoelectric applications.

Journal Article↗
PubMed2005

Field-enhanced diamagnetism in the pseudogap state of the cuprate Bi2Sr2CaCu2O(8+delta) superconductor in an intense magnetic field.

In hole-doped cuprates, Nernst experiments imply that the superconducting state is destroyed by spontaneous creation of vortices which destroy phase coherence. Using torque magnetometry on Bi2Sr2CaCu2O(8+delta), we uncover a field-enhanced diamagnetic signal M above the transition temperature Tc that increases with applied field to 32 Tesla and scales just like the Nernst signal. The magnetization results above Tc distinguish M from conventional amplitude fluctuations and strongly support the vortex scenario for the loss of phase coherence at Tc.

Journal Article↗
PubMed2005

Speeding up a single-molecule DNA device with a simple catalyst.

Recently, several groups have designed and synthesized single-molecule devices based on DNA that can switch between different configurations in response to sequential addition of fuel DNA strands. There is considerable interest in improving the speed of these "nanomotors." One approach is the use of rationally designed DNA catalysts to promote hybridization of complementary oligonucleotides. A particularly simple and robust DNA device reported by Li and Tan is comprised of a single-strand 17-base oligomer that folds into a chairlike quadruplex structure. We have identified the key rate-limiting barrier in this device as the tendency for one of the fuel strands B to fold into the quadruplex configuration of the device strand. This seriously impedes the restoration reaction. We have designed a catalytic strand to inhibit the folding of B and shown that the catalyst speeds up the restoration reaction by roughly a factor of 2. The catalyst remains effective even after repeated cycling

Base Sequence↗
PubMed2005

Controlling the size of magnetic nanoparticles using pluronic block copolymer surfactants.

We have successfully controlled the size of magnetic nanoparticles by adjusting the surfactant/solvent ratio. Gamma-Fe(2)O(3) nanoparticles of 5.6 and 12.7, and Fe(0) nanoparticles of 22.3 nm in diameter were prepared, all having spherical shape and uniform size as confirmed by TEM. Mössbauer spectra confirmed Fe(3+) for the 5.6 and 12.7 nm particles and Fe(3+) and Fe(0) for 22.3 nm particles, in good agreement with synchrotron XRD patterns. Both room temperature and 5 K H-M measurements show that 22.3 nm particles have much higher magnetization than their oxide counterparts, in agreement with their being Fe(0). T-M measurements show superparamagnetism for 5.6 and 12.7 nm particles and ferromagnetism for 22.3 nm particles.

Ferric Compounds↗
PubMed2004

Anomalous hall heat current and nernst effect in the CuCr2Se4-xBrx ferromagnet.

In a ferromagnet, an anomalous Hall heat current, given by the off-diagonal Peltier term alpha(xy), accompanies the anomalous Hall current. By combining Nernst, thermopower, and Hall experiments, we have measured how alpha(xy) varies with hole density and lifetime tau in CuCr2Se4-xBrx. At low temperatures T, we find that alpha(xy) is independent of tau, consistent with anomalous-velocity theories. Its magnitude is fixed by a microscopic geometric area A approximately 34 A(2). Our results are incompatible with some models of the Nernst effect in ferromagnets.

Journal Article↗
PubMed2004

Charge ordering, commensurability, and metallicity in the phase diagram of the layered NaxCoO2.

The phase diagram of nonhydrated NaxCoO2 has been determined by changing the Na content x using a series of chemical reactions. As x increases from 0.3, the ground state goes from a paramagnetic metal to a charge-ordered insulator (at x=1/2), then to a "Curie-Weiss metal" (around 0.70), and finally to a weak-moment magnetically ordered state (x>0.75). The unusual properties of the state at 1/2 (including particle-hole symmetry at low T and enhanced thermal conductivity) are described. The strong coupling between the Na ions and the holes is emphasized.

Journal Article↗
PubMed2004

Dissipationless anomalous Hall current in the ferromagnetic spinel CuCr2Se4-xBrx.

In a ferromagnet, an applied electric field E invariably produces an anomalous Hall current JH that flows perpendicular to the plane defined by E and M (the magnetization). For decades, the question of whether JH is dissipationless (independent of the scattering rate) has been debated without experimental resolution. In the ferromagnetic spinel CuCr2Se4-xBrx, the resistivity rho (at low temperature) may be increased by several decades by varying x (Br) without degrading M. We show that JH/E (normalized per carrier, at 5 kelvin) remains unchanged throughout. In addition to confirming the dissipationless nature of JH, our finding has implications for the generation and study of spin-Hall currents in bulk samples.

Journal Article↗
PubMed2003

Spin entropy as the likely source of enhanced thermopower in Na(x)Co2O4.

In an electric field, the flow of electrons in a solid produces an entropy current in addition to the familiar charge current. This is the Peltier effect, and it underlies all thermoelectric refrigerators. The increased interest in thermoelectric cooling applications has led to a search for more efficient Peltier materials and to renewed theoretical investigation into how electron-electron interaction may enhance the thermopower of materials such as the transition-metal oxides. An important factor in this enhancement is the electronic spin entropy, which is predicted to dominate the entropy current. However, the crucial evidence for the spin-entropy term, namely its complete suppression in a longitudinal magnetic field, has not been reported until now. Here we report evidence for such suppression in the layered oxide Na(x)Co2O4, from thermopower and magnetization measurements in both longitudinal and transverse magnetic fields. The strong dependence of thermopower on magnetic field provides a rare, unambiguous example of how strong electron-electron interaction effects can qualitatively alter electronic behaviour in a solid. We discuss the implications of our finding--that spin-entropy dominates the enhancement of thermopower in transition-metal oxides--for the search for better Peltier materials.

Journal Article↗
PubMed2003

Dependence of upper critical field and pairing strength on doping in cuprates.

We have determined the upper critical field Hc2 as a function of hole concentration in bismuth-based cuprates by measuring the voltage induced by vortex flow in a driving temperature gradient (the Nernst effect), in magnetic fields up to 45 tesla. We found that Hc2 decreased steeply as doping increased, in both single and bilayer cuprates. This relationship implies that the Cooper pairing potential displays a trend opposite to that of the superfluid density versus doping. The coherence length of the pairs xi(0) closely tracks the gap measured by photoemission. We discuss implications for understanding the doping dependence of the critical temperature Tc0.

Journal Article↗
PubMed2002

Insulating behavior of lambda-DNA on the micron scale.

We have investigated the electrical conductivity of lambda-DNA using DNA covalently bonded to Au electrodes. Thiol-modified dTTP was incorporated into the "sticky" ends of bacteriophage lambda-DNA using DNA polymerase. Two-probe measurements on such molecules provide a hard lower bound for the resistivity rho>10(6)Omega cm at bias potentials up to 20 V, in conflict with recent claims of moderate to high conductivity. By direct imaging, we show that the molecules are present after the measurements. We stress the importance of eliminating salt residues in these measurements.

Bacteriophage lambda↗
PubMed2002

High field phase diagram of cuprates derived from the Nernst effect.

Measurements of the Nernst signal in the vortex-liquid state of the cuprates to high fields (33 T) reveal that vorticity extends to very high fields even close to the zero-field critical temperature T(c0). In overdoped La2-xSrxCuO4, we show that the upper critical field H(c2)(T) curve does not end at T(c0), but at a much higher temperature. These results imply that T(c0) corresponds to a loss in phase rigidity rather than a vanishing of the pairing amplitude. An intermediate field H*(T)<<H(c2)(T) is shown to be the field scale for the flux-flow resistivity.

Journal Article↗
PubMed2001

Particle-hole symmetry in the antiferromagnetic state of the cuprates.

In the layered cuprate perovskites, the occurrence of high-temperature superconductivity seems deeply related to the unusual nature of the hole excitations. The limiting case of a very small number of holes diffusing in the antiferromagnetic (AF) background may provide important insights into this problem. We have investigated the transport properties in a series of crystals of YBa(2)Cu(3)O(y), and found that the temperature dependencies of the Hall coefficient R(H) and thermopower S change abruptly as soon as the AF phase boundary is crossed. In the AF state at low temperatures T, both R(H) and S are unexpectedly suppressed to nearly zero over a broad interval of T. We argue that this suppression arises from near-exact symmetry in the particle-hole currents. From the trends in R(H) and S, we infer that the symmetry is increasingly robust as the hole density x becomes very small (x approximately 0.01). We discuss implications for electronic properties both within the AF state and outside.

Journal Article↗
PubMed2001

Superconductivity in the non-oxide perovskite MgCNi3.

The interplay of magnetic interactions, the dimensionality of the crystal structure and electronic correlations in producing superconductivity is one of the dominant themes in the study of the electronic properties of complex materials. Although magnetic interactions and two-dimensional structures were long thought to be detrimental to the formation of a superconducting state, they are actually common features of both the high transition-temperature (Tc) copper oxides and low-Tc material Sr2RuO4, where they appear to be essential contributors to the exotic electronic states of these materials. Here we report that the perovskite-structured compound MgCNi3 is superconducting with a critical temperature of 8 K. This material is the three-dimensional analogue of the LnNi2B2C family of superconductors, which have critical temperatures up to 16 K (ref. 2). The itinerant electrons in both families of materials arise from the partial filling of the nickel d-states, which generally leads to ferromagnetism as is the case in metallic Ni. The high relative proportion of Ni in MgCNi3 suggests that magnetic interactions are important, and the lower Tc of this three-dimensional compound-when compared to the LnNi2B2C family-contrasts with conventional ideas regarding the origins of superconductivity.

Journal Article↗
PubMed2001

Giant enhancement of the thermal Hall conductivity kappa(xy) in the superconductor YBa(2)Cu(3)O(7).

In high-purity YBa(2)Cu(3)O(7), the (weak-field) thermal Hall conductivity kappa(xy) is observed to increase a thousand-fold between 90 and 30 K. The inferred quasiparticle lifetime tau increases a hundred-fold starting below 90 K, in disagreement with a recent photoemission experiment. We show that kappa(xy) exhibits a specific scaling behavior below approximately 30 K. This scaling may bear on the issue of whether Landau quantization of the quasiparticle states occurs.

Journal Article↗
PubMed2000

Determining the Wiedemann-Franz ratio from the thermal hall conductivity: application to Cu and YBa2Cu3O6.95.

The Wiedemann-Franz (WF) ratio compares the thermal and electrical conductivities in a metal. We describe a new way to determine its value, based on the thermal Hall conductivity. The technique is applied to copper and to untwinned YBaCuO. In the latter, we uncover a T-linear dependence and suppression of the Hall-channel WF ratio. We discuss the implications of this suppression. The general suppression of the WF ratio in systems with predominant electron-electron scattering is discussed.

Journal Article↗