Biomedical subjects

N S Sariciftci

Publications and source records attributed to N S Sariciftci.

4 recordsLinked to original sources

PubMed2006

Photoinduced charge and energy transfer involving fullerene derivatives.

In this feature article, a brief overview over the photoinduced energy and charge transfer mechanisms involving fullerenes will be presented. The photoinduced charge separation between organic donor and acceptor molecules is the basic photophysical mechanism for natural photosynthesis and nearly all organic solar cell concepts. We will give a short introduction to the mechanisms of excited state charge transfer and resonant energy transfer and present examples of relevant applications in organic optoelectronics and photodynamic tumor therapy.

Journal Article↗

PubMed2005

Bimolecular recombination coefficient as a sensitive testing parameter for low-mobility solar-cell materials.

Bimolecular charge carrier recombination has been clarified in bulk-heterojunction solar cells based on a blend of regioregular poly(3-hexylthiophene) and 1-(3-methoxycarbonyl)propyl-1-phenyl-[6,6]-methanofullerene using the time-of-flight method. We show how bimolecular recombination influences the charge carrier transport, how it limits the efficiency of low-mobility solar cells, and how to estimate the bimolecular recombination coefficient. We found that bimolecular recombination in these efficient photovoltaic materials is orders of magnitude slower as compared to Langevin recombination expected for low-mobility materials. This effect is inherent to the nanomorphology of the bicontinuous interpenetrating network creating separate pathways for electrons and holes, and paves the way for the fabrication of bulk-heterojunction solar cells where bimolecular recombination is not the limiting factor.

Journal Article↗

PubMed2005

Kelvin probe force microscopy study on conjugated polymer/fullerene bulk heterojunction organic solar cells.

We conducted a comprehensive Kelvin probe force microscopy (KPFM) study on a classical organic solar cell system consisting of MDMO-PPV/PCBM blends. The KPFM method yields the information of topography and local work function at the nanometer scale. Experiments were performed either in the dark or under cw laser illumination at 442 nm. We identified distinct differences in the energetics on the surface of chlorobenzene and toluene cast blend films. Together with high-resolution scanning electron microscopy (SEM) experiments we were able to interpret the KPFM results and to draw some conclusions for the electron transport toward the cathode in the solar cell configuration. The results suggest that surfaces of toluene cast films exhibit a morphologically controlled hindrance for electron propagation toward the cathode, which is usually evaporated on top of the films in the solar cell device configuration.

Electric Power Supplies↗

PubMed2003

Time domain investigation of the intrachain vibrational dynamics of a prototypical light-emitting conjugated polymer.

Coherent nuclear motion of the carbon backbone is monitored in real time in substituted poly(phenylene)-vinylene in both excited and ground electronic state using sub-10-fs light pulses. Characteristic features of the intrachain vibrational dynamics are obtained. We observe vibrational dephasing in the excited state within 1 ps (time constant T(2e) approximately 300 fs). These findings are in agreement with the molecular picture for photoexcitation in conjugated polymers.

Journal Article↗