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Nikhil Koratkar

Publications and source records attributed to Nikhil Koratkar.

4 recordsLinked to original sources

Suppressing electrostatic screening in nanostructured electrode arrays.

An individual nanostructure provides very high electric field enhancement because the sharp curvature of the nanostructure tip amplifies the local electric field near the apex tip. However any practical nanostructured electrode is comprised of an ensemble (array) of nanostructures. In such systems, mutual electrostatic shielding (or screening) severely limits the maximum achievable electric field enhancement. In this paper, we discuss three approaches for suppression of shielding. These include--(1) reducing anode-to-cathode distance to less than the nanostructure-to-nanostructure spacing, (2) increasing length of selected individual nanostructures within the array, and (3) design of electrodes with multistage amplification. We show that these approaches are effective in alleviating electrostatic shielding and that the enhancement factor of the electrode array (ensemble) can be engineered to match that of the individual (isolated) nanostructure.

Computer Simulation↗

Viscoelasticity in carbon nanotube composites.

Polymer composites reinforced by carbon nanotubes have been extensively researched for their strength and stiffness properties. Unless the interface is carefully engineered, poor load transfer between nanotubes (in bundles) and between nanotubes and surrounding polymer chains may result in interfacial slippage and reduced performance. Interfacial shear, although detrimental to high stiffness and strength, could result in very high mechanical damping, which is an important attribute in many commercial applications. We previously reported evidence of damping in nanocomposites by measuring the modal response (at resonance) of cantilevered beams with embedded nanocomposite films. Here we carry out direct shear testing of epoxy thin films containing dense packing of multiwalled carbon nanotube fillers and report strong viscoelastic behaviour with up to 1,400% increase in loss factor (damping ratio) of the baseline epoxy. The great improvement in damping was achieved without sacrificing the mechanical strength and stiffness of the polymer, and with minimal weight penalty. Based on the interfacial shear stress (approximately 0.5 MPa) at which the loss modulus increases sharply for our system, we conclude that the damping is related to frictional energy dissipation during interfacial sliding at the large, spatially distributed, nanotube-nanotube interfaces.

Journal Article↗

Temperature effects on resistance of aligned multiwalled carbon nanotube films.

Electrical transport in vertically aligned films of multiwalled carbon nanotubes has been investigated in the -150 degrees C to 300 degrees C temperature range (all the tests were conducted in air at atmospheric pressure). In all the cases, the nanotube film exhibited a semi-conducting behavior, with the film resistance decreasing with increasing temperature. Removal of amorphous carbon contamination (via plasma etching) significantly improved the nanotube film's sensitivity to temperature changes (particularly in the 20 degrees C to 200 degrees C temperature range). All the of films tested in this study showed a consistent, repeatable behavior that was independent of the nanotube film length. The temperature sensitivity of the nanotube films was also found to be independent of the heating/cooling rates and without hysteresis. Because of the excellent repeatability and stability of the results, it is conceived that miniaturized temperature sensors could be designed using such aligned multiwalled nanotube films.

Carbon↗

Miniaturized gas ionization sensors using carbon nanotubes.

Gas sensors operate by a variety of fundamentally different mechanisms. Ionization sensors work by fingerprinting the ionization characteristics of distinct gases, but they are limited by their huge, bulky architecture, high power consumption and risky high-voltage operation. Here we report the fabrication and successful testing of ionization microsensors featuring the electrical breakdown of a range of gases and gas mixtures at carbon nanotube tips. The sharp tips of nanotubes generate very high electric fields at relatively low voltages, lowering breakdown voltages several-fold in comparison to traditional electrodes, and thereby enabling compact, battery-powered and safe operation of such sensors. The sensors show good sensitivity and selectivity, and are unaffected by extraneous factors such as temperature, humidity, and gas flow. As such, the devices offer several practical advantages over previously reported nanotube sensor systems. The simple, low-cost, sensors described here could be deployed for a variety of applications, such as environmental monitoring, sensing in chemical processing plants, and gas detection for counter-terrorism.

Air↗