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O Greffier

Publications and source records attributed to O Greffier.

6 recordsLinked to original sources

Local velocity measurements in heterogeneous and time-dependent flows of a micellar solution.

We present and discuss the results of pointwise velocity measurements performed on a viscoelastic micellar solution made of cetyltrimethylammonium bromide and sodium salicylate in water, respectively, at the concentrations of 50 and 100 mmol. The sample is contained in a Couette device and subjected to flow in the strain controlled mode. This particular solution shows shear banding and, in a narrow range of shear rates at the right end of the stress plateau, apparent shear thickening occurs. Time-dependent recordings of the shear stress in this range reveal that the flow has become unstable and that large sustained oscillations of the shear stress and of the first normal stresses difference emerge and grow in the flow. Local pointwise velocity measurements clearly reveal a velocity profile typical of shear banding when the imposed shear rate belongs to the plateau, but also important wall slip in the entire range of velocity gradients investigated. In the oscillations regime, the velocity is recorded as a function of time at a fixed point close to the rotor of the Couette device. The time-dependent velocity profile reveals random fluctuations but, from time to time, sharp decreases much larger than the standard deviation are observed. An attempt is made to correlate these strong variations with the stress oscillations and a correlation coefficient r is computed. However, the small value found for the coefficient r does not allow us to draw a final conclusion as concerns the correlation between stress oscillations and velocity fast decreases.

Journal Article↗

Temporal oscillations of the shear stress and scattered light in a shear-banding--shear-thickening micellar solution.

The results of optical and rheological experiments performed on a viscoelastic solution (cetyltrimethylammonium bromide + sodium salicylate in water) are reported. The flow curve has a horizontal plateau extending between two critical shear rates characteristic of heterogeneous flows formed by two layers of fluid with different viscosities. These two bands which also have different optical anisotropy are clearly seen by direct observation in polarized light. At the end of the plateau, apparent shear thickening is observed in a narrow range of shear rates; in phase oscillations of the shear stress and of the first normal stress difference are recorded in a shearing device operating under controlled strain. The direct observation of the annular gap of a Couette cell in a direction perpendicular to a plane containing the vorticity shows that the turbidity of the whole sample also undergoes time dependent variations with the same period as the shear stress. However no banding is observed during the oscillations and the flow remains homogeneous.

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Thickness fluctuations in turbulent soap films.

Rapidly flowing soap films provide a simple and attractive system to study two-dimensional hydrodynamics and turbulence. By measuring the rapid fluctuations of the thickness of the film in the turbulent regime, we find that the statistics of these fluctuations closely resemble those of a passive scalar field in a turbulent flow. The scalar spectra are well described by Kolmogorov-like scaling while the high-order moments show clear deviations from regular scaling just like dye or temperature fluctuations in 3D turbulent flows.

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Dynamic light scattering from lyotropic lamellar phases subjected to a flow field.

Dynamic light scattering experiments on lyotropic lamellar phases of brine and surfactant subjected to a flow field have been realized. The obtained results reveal that the relaxation times measured depend strongly on the velocity of the flow. This dependence is indicative of an increase of the effective elasticity modulus K and a decrease of the effective compressibility modulus (-)B of the lamellar phase with the flow velocity. This leads to the conclusion that the shear can induce a suppression of the undulation fluctuations of the bilayers of the lamellar phase. Our results show also that the rigidity of the membranes decreases as the salt concentration of the sample increases.

Biophysics↗

Coupling between flow and structure for a lamellar surfactant phase

The flow-structure relation of lamellar phases is studied using rheometry and cross-polarized microscopy under flow. The equilibrium phases show different defects. Low salinities lead to very viscous, "onion" phases, whereas at high salinity, a low viscosity plane lamellar phase is found. Under shear, the latter shows a sudden transition to a viscoelastic gel, with a texture and viscosity very similar to that of the onions. Gelation occurs after a certain delay time, increasing rapidly with salinity, by the nucleation of onions. This allows one to relate the delay time to the defect energy.

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Numerical study of grid turbulence in two dimensions and comparison with experiments on turbulent soap films.

Numerical simulations of two dimensional channel flow behind an array of cylinders are carried out for high Reynolds numbers. Results for the energy density and enstrophy spectra, as well as for velocity and vorticity differences, are presented. The results compare favorably with recent experiments carried out with turbulent soap films. Some marked deviations from expected behavior are found for the enstrophy spectrum and for moments of vorticity increments.

Journal Article↗