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O W Wai

Publications and source records attributed to O W Wai.

4 recordsLinked to original sources
PubMed2001

Parameter estimation for suspended sediment transport processes under random waves.

This paper presents a parameter estimation method for suspended sediment transport processes subject to random wave environments. An objective function was constructed based on measurements of suspended sediment concentration profiles and the governing equation of sediment transport. The Chebyshev least square method was employed to approximate the process parameters, i.e. vertical eddy diffusivity (epsilon) and net vertical velocity (w). The objective function of sediment transport processes with Chebyshev's parameters is well posed and does not require boundary conditions. First, second, and third order epsilon and w Chebyshev orthogonal functions were determined for monochromatic (MONO), narrow-banded (NBR) and broad-banded (BBR) random wave conditions. In the BBR and NBR conditions, the best fit Chebyshev approximations of epsilon and w were 2nd degree, while the best approximations in the MONO condition were 2nd degree for epsilon and 1st degree for w. The Chebyshev method provides a quick, accurate and direct estimation of two prime parameters in sediment transport dynamics.

Journal Article↗
PubMed2001

The effect of flow-through leaching on the diffusivity of heavy metals in stabilized/solidified wastes.

The flow-through leaching test is a test method employed to study the leaching behavior of monolithic stabilized/solidified (S/S) hazardous wastes under the condition that the leachate flows through the sample. This method simulates the leaching process of the S/S hazardous waste disposed under a particular landfill condition when the S/S waste is more permeable than its surrounding materials or when the deterioration of the solidified waste form has reached a state that ground water can flow-through the waste via the porosity system of the S/S waste matrix. This paper describes a study on the long-term performance of the cement-based S/S heavy metal wastes using a flow-through leaching test method. Two series of leaching tests with different synthetic heavy metal waste samples were carried out. The S/S samples were made from five types of heavy metals with two kinds of binders. The metals were Pb(2+), Zn(2+), Cu(2+), Ni(2+) (positive ions as nitrates), and Cr(6+) (a negative ion as potassium dichromate), and the binders were type I ordinary portland cement (OPC) and pulverised fuel ash (PFA). The model developed by Godbee and Joy for simulating the leaching behavior was modified to estimate the diffusivity parameter in this study. The results obtained indicate that since the matrix of the solidified waste in a flow-through leaching tests is always being degraded, the values of diffusivities increase continuously during the leaching period. The diffusivity variation range was from 10(-13) to 10(-3)cm(2)/s, and were normally higher than those obtained from other test methods such as ANS 16.1 test and other dynamic leaching tests.

Decontamination↗
PubMed2001

Chemical forms of Pb, Zn and Cu in the sediment profiles of the Pearl River Estuary.

The chemical forms of heavy metals (Pb, Zn and Cu) in sediment cores of the Pearl River Estuary were studied using a sequential chemical extraction method. The isotope ratios of 206Pb/207Pb in various chemical fractions were also measured to assess the potential Pb sources. Zinc and Cu were mainly associated with the residual fraction. The Fe-Mn oxide and organic/sulphide fractions were the next important phases for Zn and Cu, respectively. For Pb, different chemical partitioning patterns were found among different sediment cores. Most Pb was associated with the residual fraction in the sediments. In some sediment profiles, the major phase of Pb in the top layers was the Fe-Mn oxide fraction. The proportion of Pb in the Fe-Mn oxide fraction decreased significantly with increasing depth. Among the different depths, the 206Pb/207Pb isotope ratios in the residual fraction remained fairly stable, with a mean value of 1.202, which may represent the natural background value. The 206Pb/207Pb ratios in the exchangeable fraction were the lowest among the five fractions, particularly in top sediments, showing the anthropogenic inputs of heavy metals from recent rapid industrial development in the surrounding region. For the other three non-residual fractions, there was a similar trend of increasing 206Pb/207Pb ratios down the profile. Results from this study are useful in assessing both the chemical changes for heavy metals in marine sediments and the potential of heavy metal release into the water environment of an estuary area.

China↗