Biomedical subjects

P Cicuta

Publications and source records attributed to P Cicuta.

4 recordsLinked to original sources

PubMed2005

Viscoelasticity of a protein monolayer from anisotropic surface pressure measurements.

We present a method to completely characterize the viscoelasticity of Langmuir monolayers. In contrast to existing techniques, both the compression and shear moduli are determined at the same time, in a single experiment and with a standard apparatus. This approach relies on the measurement of anisotropy in the surface pressure: the tension is measured in orientations perpendicular and parallel to the compression direction. We apply this technique to the study of beta-lactoglobulin spread monolayers, a system that has been shown to develop a shear modulus at high concentration. Beta-lactoglobulin monolayers are interesting both because of their importance in food science and because they exhibit universally slow dynamical behavior that is not fully understood. Our results confirm that the compressional modulus dominates the total viscoelastic response and also provide a complex shear modulus, emerging above a critical concentration. We are able to describe how each of the dynamical response moduli is related to the surface concentration and to the equilibrium osmotic pressure.

Algorithms↗

PubMed2004

Photonic gaps in cholesteric elastomers under deformation.

Cholesteric liquid crystal elastomers have interesting and potentially very useful photonic properties. In an ideal monodomain configuration of these materials, one finds a Bragg reflection of light in a narrow wavelength range and a particular circular polarization. This is due to the periodic structure of the material along one dimension. In many practical cases, the cholesteric rubber possesses a sufficient degree of quenched disorder, which makes the selective reflection broadband. We investigate experimentally the problem of how the transmittance of light is affected by mechanical deformation of the elastomer, and the relation to changes in liquid crystalline structure. We explore a series of samples which have been synthesized with photonic stop gaps across the visible range. This allows us to compare results with detailed theoretical predictions regarding the evolution of stop gaps in cholesteric elastomers.

Journal Article↗

PubMed2002

Evolution of photonic structure on deformation of cholesteric elastomers.

We subject a monodomain cholesteric liquid crystal elastomer to uniaxial strain perpendicular to its helical axis and study the response of its texture to deformation. A combination of mechanical, optical, and x-ray scattering measurements confirms the prediction for the director rotation, coarsening, and then unwinding the cholesteric helix. The study of optical absorption of circularly polarized light quantifies the complex dependence of the photonic band-gap structure on strain and directly relates to the microscopic deformation of elastomer. Agreement is found with the recently proposed theoretical prediction of the photonic structure of cholesteric elastomers.

Journal Article↗

PubMed2000

Equilibrium and nonequilibrium fluctuations at the interface between two fluid phases

We have performed small-angle light-scattering measurements of the static structure factor of a critical binary mixture undergoing diffusive partial remixing. An uncommon scattering geometry integrates the structure factor over the sample thickness, allowing different regions of the concentration profile to be probed simultaneously. Our experiment shows the existence of interface capillary waves throughout the macroscopic evolution to an equilibrium interface, and allows us to derive the time evolution of surface tension. Interfacial properties are shown to attain their equilibrium values quickly compared to the system's macroscopic equilibration time.

Journal Article↗