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R Borja

Publications and source records attributed to R Borja.

23 records · Page 2Linked to original sources

A kinetic study of anaerobic digestion of olive mill wastewater at mesophilic and thermophilic temperatures.

The kinetics of the anaerobic digestion of olive mill wastewater (OMW) was studied in the mesophilic and thermophilic ranges of temperature. Two completely mixed continuous flow bioreactors operating at 35 degrees C and 55 degrees C and with an average biomass concentration of 5.45 g VSS litre(-1) were used. The thermophilic reactor worked satisfactorily between hydraulic retention times (HRT) of 10 to 40 days, removing between 94.6 and 84.4% of the initial chemical oxygen demand (COD). In contrast, the mesophilic reactor showed a marked decrease in substrate utilization and methane production at a HRT of 10 days. TVFA levels and the TVFA/alkalinity ratio were higher and close to the suggested limits for digester failure. The yield coefficient for methane production (1 CH(4) STP g(-1) COD(added)) was 28% higher in the thermophilic process than in the mesophilic one. Macroenergetic parameters, calculated using Guiot's kinetic model, gave yield coefficients for the biomass (Y) of 0.18 (mesophilic) and 0.06 g VSS g(-1) COD (thermophilic) and specific rates of substrate uptake for cell maintenance (m) of 0.12 (mesophilic) and 0.27 g COD g(-1) VSS.day(-1) (thermophilic). The experimental results showed the rate of substrate uptake (R(s); g COD g(-1) VSS.day(-1)), correlated with the concentration of biodegradable substrate (S(b); g COD litre(-1)), through an equation of the Michaelis-Menten type for the two temperatures used.

Journal Article↗

Effect of aerobic pretreatment with Aspergillus terreus on the anaerobic digestion of olive-mill wastewater.

A kinetic study was carried out on the anaerobic digestion of olive-mill wastewater (OMW) and OMW that was previously fermented with Aspergillus terreus. The bioreactors used were batch fed and contained saponite as support for the mediating bacteria. The anaerobic digestion process followed first-order kinetics, from which the kinetic constant A was calculated using a non-linear regression. This kinetic parameter was influenced by the pretreatment carried out, and was 3.7 times higher for pretreated OMW than for untreated OMW. The anaerobic processing of pretreated OMW seemingly involved no inhibition phenomena as the biotoxicity and the total phenolic compound content (analysed by HPLC) were reduced by 71.2% and 77.9% respectively as a result of the pretreatment. Finally, the yield coefficient of methane production was 0.345 litres of methane (at standard temperature and pressure)/g of chemical oxygen demand, that is, 23% higher than that provided by untreated wastewater.

Anaerobiosis↗

Kinetics of anaerobic digestion of soft drink wastewater in immobilized cell bioreactors.

A kinetic study of the anaerobic digestion of soft drink wastewater was undertaken, using bioreactors containing various suspended supports (bentonite, zeolite, sepiolite, saponite and polyurethane foam), on to which the microorganisms effecting the purification were immobilized. Assuming the overall anaerobic digestion process conforms to first-order kinetics, the specific rate constants, K0, derived from the reactors with saponite and sepiolite (magnesium silicates) were approximately twice those from bentonite and zeolite (aluminium silicates) and almost five times higher than in the control reactor (without support); the polyurethane support showed an intermediate behaviour. The methanogenic activity increased linearly with COD load, with saponite and sepiolite supports showing the highest values. The average yield coefficient of methane was 325 cm3 CH4 STP g-1 COD and the percentage elimination of COD was 77.8%; these values were not significantly altered by the type of support used.

Bacteria, Anaerobic↗

Kinetic study of anaerobic digestion of fruit-processing wastewater in immobilized-cell bioreactors.

The kinetics of the anaerobic digestion of a fruit-processing wastewater [chemical oxygen demand (COD) = 5.1 g/l] were investigated. Laboratory experiments were carried out in bioreactors containing supports of different chemical composition and features, namely bentonite and zeolite (aluminum silicates), sepiolite and saponite (magnesium silicates) and polyurethane foam, to which the microorganisms responsible for the process adhered. The influence of the support medium on the kinetics was compared with a control digester with suspended biomass. Assuming the overall anaerobic digestion process conforms to first-order kinetics, the specific rate constant, K0, was determined for each of the experimental reactors. The average values obtained were: 0.080 h-1 (bentonite); 0.103 h-1 (zeolite); 0.180 h-1 (sepiolite); 0.198 h-1 (saponite); 0.131 h-1 (polyurethane); and 0.037 h-1 (control). The results indicate that the support used to immobilize the micro-organisms had a marked influence on the digestion process; the results were significant at the 95% confidence level. Methanogenic activity increased linearly with COD, with the saponite and sepiolite supports showing the highest values. The yield coefficient of methane was 270 ml of methane (under standard temperature and pressure conditions)/g of COD. The average elimination of COD was 89.5%.

Anaerobiosis↗