Biomedical subjects

R Vacher

Publications and source records attributed to R Vacher.

At least 19 recordsLinked to original sources

PubMed2006

Hyper-Raman scattering from vitreous boron oxide: coherent enhancement of the boson peak.

Hyper-Raman scattering spectra of vitreous B(2)O(3) are compared to Raman scattering ones. Particular attention is given to the low-frequency boson peak which relates to out-of-plane rigid librations of planar structural units, mostly boroxols. While the Raman strength can be accounted for by the motions of single units, the hyper-Raman signal exhibits a unequaled enhancement due to coherent librations of several boroxols. This important distinction is explained by the different symmetry properties of the polarizability and hyperpolarizability tensors of the structural units.

Journal Article↗

PubMed2006

Glass-specific behavior in the damping of acousticlike vibrations.

High frequency sound is observed in lithium diborate glass, Li2O-2B2O3, using Brillouin scattering of light and x rays. The sound attenuation exhibits a nontrivial dependence on the wave vector, with a remarkably rapid increase towards a Ioffe-Regel crossover as the frequency approaches the boson peak from below. An analysis of literature results reveals that the boson-peak frequency is closely related with a Ioffe-Regel limit for sound in many glasses. We conjecture that this relation, specific to glassy materials, might be rather common among them.

Journal Article↗

PubMed2003

Observation of the onset of strong scattering on high frequency acoustic phonons in densified silica glass.

The linewidth of longitudinal acoustic waves in densified silica glass is obtained by inelastic x-ray scattering. It increases with a high power alpha of the frequency up to a crossover where the waves experience strong scattering. We find that alpha is at least 4, and probably larger. Resonance and hybridization of acoustic waves with the boson-peak modes seems to be a more likely explanation for these findings than Rayleigh scattering from disorder.

Journal Article↗

PubMed2000

Hyper-raman scattering observation of the boson peak in vitreous silica

Hyper-Raman spectroscopy is used to investigate low frequency vibrations of various silica glasses. A strong boson peak is observed. The corresponding modes are inactive in infrared and Raman spectra, and are nonacoustic in nature. The shape of this boson peak essentially matches the total density of vibrational states (DOS), with a constant coupling coefficient C. This and other indications suggest that these modes actually dominate the DOS of silica.

Journal Article↗

PubMed1996