The bis(eta 5-cyclopentadienyl)methylzirconium(IV) methyltris(pentafluorophenyl)borate ion pair
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Biomedical subjects
Publications and source records attributed to RF Jordan.
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The crystal structure of hexa-&mgr;-hydroxo-dodecamethylocta-&mgr;(3)-oxo-dodecagallium(III) bis[tetrakis(pentafluorophenyl)borate(III)] chlorobenzene disolvate dihydrate, [Ga(12)(CH(3))(12)(&mgr;(3)-O)(8)(&mgr;-OH)(6)](C(24)F(20)B)(2). 2C(6)H(5)Cl.2H(2)O, is reported. The gallium-oxo-hydroxide dication is located on an inversion center and adopts a cage structure composed of 12 fused Ga(3)O(3) rings and is associated with the hydrate molecules and the [B(C(6)F(5))(4)](-) anions through hydrogen bonds and one O-H.pi-ring interaction. Disordered chlorobenzene solvent molecules are also present in the crystal structure.
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