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Roberto Melzi

Publications and source records attributed to Roberto Melzi.

2 recordsLinked to original sources

Large surface mapping by a unilateral NMR scanner.

The nuclear magnetic resonance (NMR) surface scanner, which provides images of sample surfaces larger than the probe dimension, has been realized using a single-sided device. Although conditioned by distortion effects originated by convolution between the sensitive volume of the probe and the space structures to be imaged, the scanner is able to provide images with good spatial resolution. The images obtained by the surface scanner can be made sensitive to relaxation parameters, magnetization or molecular self-diffusion; also, the dimension perpendicular to the sample surface can be scanned by varying the depth from which the probe detects the sample signal. It may scan surfaces arbitrarily large and with some degree of curvature. This aspect, together with the noninvasive characteristic of the apparatus, indicates that the surface scanner could be used profitably in the field of cultural heritage, where it could provide NMR maps of frescos, paintings on wood, marble artifacts, books and others.

Equipment Design↗

(EDT-TTF-CONH2)6[Re6Se8(CN)6], a metallic Kagome-type organic-inorganic hybrid compound: electronic instability, molecular motion, and charge localization.

(EDT-TTF-CONH2)6[Re6Se8(CN)6], space group R, was prepared by electrocrystallization from the primary amide-functionalized ethylenedithiotetrathiafulvalene, EDT-TTF-CONH2 (E(1/2)1 = 0.49 V vs SCE in CH3CN), and the molecular cluster tetraanion, [Re6Se8(CN)6]4- (E(1/2) = 0.33 V vs SCE in CH3CN), equipped with hydrogen bond donor and hydrogen bond acceptor functionalities, respectively. Its Kagome topology is unprecedented for any TTF-based materials. The metallic state observed at room temperature has a strong two-dimensional character, in coherence with the Kagome lattice symmetry, and the presence of minute amounts of [Re6Se8(CN)6](3-)* identified by electron spin spectroscopy. A structural instability toward a distorted form of the Kagome topology of lesser symmetry is observed at ca. 180 K. The low-temperature structure is associated with a localized, electrically insulating electronic ground state and its magnetic susceptibility accounted for by a model of uniform chains of localized S = 1/2 spins in agreement with the 100 K triclinic crystal structure and band structure calculations. A sliding motion, within one out of the three (EDT-TTF-CONH2)2 dimers coupled to the [Re6Se8(CN6)(3-)*]/[Re6Se8(CN6)4-] proportion at any temperature, and the electronic ground state of the organic-inorganic hybrid material are analyzed on the basis of ESR, dc conductivity, 1H spin-lattice relaxation, and static susceptibility data which qualify a Mott localization in [EDT-TTF-CONH2]6[Re6Se8(CN)6]. The coupling between the metal-insulator transition and a structural transition allows for the lifting of a degeneracy due to the ternary axis in the high temperature, strongly correlated metallic phase which, in turn, leads to Heisenberg chains at low temperature.

Crystallization↗