Ryuji Higashinaka | PubMed Health

PubMed2005

Field-induced transition on a triangular plane in the spin-ice compound Dy2Ti2O7.

The origin of the lowest-temperature anomaly reported several years ago using a polycrystalline sample of the spin-ice compound Dy2Ti2O7 has remained unresolved. Here we finally clarify its origin by susceptibility measurements down to 65 mK using single crystals under accurate control of the magnetic fields in two independent directions. We demonstrate that the transition is induced under a subtle field combination that precisely cancels the nearest-neighbor spin interactions acting on the spins on the triangular lattice within the pyrochlore structure. Contrary to the other two field-induced transitions, this transition is driven only by the interactions beyond the nearest neighbors. Our observation thus provides the first qualitative evidence for the essential importance of the dipolar interaction beyond the nearest neighbors in the spin ice.

Journal Article↗

PubMed2004

[Analysis of residual solvents in natural flavorings by headspace GC using the standard addition method].

Headspace GC using the standard addition method has been developed for the simultaneous determination of organic solvents in natural flavorings. The procedure can be outlined as follows: an aliquot of the sample is transferred to a 10 mL vial. To each vial, a DMSO solution containing solvents at different concentrations is added as the standard solution. The vials are kept at 50 degrees C (for automatic injection) or 40 degrees C (for hand-operated injection) for 40 minutes. One mL of the vapor phase in each vial is injected into a gas chromatograph equipped with an Aquatic-2 column (0.25 mm i.d. x 60 m). To evaluate this method, we conducted a performance study in collaboration with 10 laboratories, using ginger oleoresin. We analyzed 6 solvents (methanol, 2-propanol, acetone, dichloromethane, hexane, and 1,1,2-trichloroethene) for which the maximum residue limits are established in Japan's Specifications and Standards for Food Additives. Methanol and acetone existed in the ginger oleoresin, so only the other that four kinds of solvents were added to it. Eight of the laboratories used automatic injection, while the remaining two used hand-operated injection. Statistical analyses were conducted on the data obtained from the 8 laboratories. Repeatability standard deviations (RSDr) ranged from 4.3 to 11.4%, and reproducibility standard deviations (RSDR) ranged from 8.4 to 19.0%.

2-Propanol↗