A cationic hydroxo-bridged dinuclear gallium complex.
Explore the source record for details and available documents.
Journal Article↗
Biomedical subjects
S Dagorne
Publications and source records attributed to S Dagorne.
Bis(isopropylamino)methylcarbenium tetrakis(pentafluorophenyl)gallate.
The title compound, [MeC(NH(i)Pr)(2)][Ga(C(6)F(5))(4)] crystallizes as discrete ions forming interionic hydrogen bonds of the type N-H.F.
Journal Article↗
A dicationic gallium-oxo-hydroxide cage compound
The crystal structure of hexa-&mgr;-hydroxo-dodecamethylocta-&mgr;(3)-oxo-dodecagallium(III) bis[tetrakis(pentafluorophenyl)borate(III)] chlorobenzene disolvate dihydrate, [Ga(12)(CH(3))(12)(&mgr;(3)-O)(8)(&mgr;-OH)(6)](C(24)F(20)B)(2). 2C(6)H(5)Cl.2H(2)O, is reported. The gallium-oxo-hydroxide dication is located on an inversion center and adopts a cage structure composed of 12 fused Ga(3)O(3) rings and is associated with the hydrate molecules and the [B(C(6)F(5))(4)](-) anions through hydrogen bonds and one O-H.pi-ring interaction. Disordered chlorobenzene solvent molecules are also present in the crystal structure.
Journal Article↗