Biomedical subjects

S I Simdyankin

Publications and source records attributed to S I Simdyankin.

5 recordsLinked to original sources

PubMed2006

Universal features of terahertz absorption in disordered materials.

Using an analytical theory, experimental terahertz time-domain spectroscopy data, and numerical evidence, we demonstrate that the frequency dependence of the absorption coupling coefficient between far-infrared photons and atomic vibrations in disordered materials has the universal functional form, C(omega)=A+Bomega(2), where the material-specific constants A and B are related to the distributions of fluctuating charges obeying global and local charge neutrality, respectively.

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PubMed2005

New type of charged defect in amorphous chalcogenides.

We report on density-functional-based tight-binding simulations of a series of amorphous arsenic sulfide models. In addition to the charged coordination defects previously proposed to exist in chalcogenide glasses, a novel defect pair, [As(4)](-)-[S(3)](+), consisting of a fourfold coordinated arsenic site in a seesaw configuration and a threefold coordinated sulfur site in a near-planar trigonal configuration, was found in several models. The valence-alternation pairs [S(3)](+)-S-1 are converted into [As(4)](-)-[S(3)](+) pairs under HOMO-to-LUMO electronic excitation. This structural transformation is accompanied by a decrease in the size of the HOMO-LUMO band gap, which suggests that such transformations could contribute to photodarkening in these materials.

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PubMed2003

Relationship between dynamical heterogeneities and stretched exponential relaxation.

We identify dynamical heterogeneities as an essential prerequisite for stretched exponential relaxation in dynamically frustrated systems. This heterogeneity takes the form of ordered domains of finite but diverging lifetime for particles in atomic or molecular systems, or spin states in magnetic materials. At the onset of the dynamical heterogeneity, the distribution of time intervals spent in such domains or traps becomes stretched exponential at long times. We rigorously show that once this is the case the autocorrelation function of the renewal process formed by these time intervals is also a stretched exponential at long times.

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PubMed2002

Characterization of the stretched-exponential trap-time distributions in one-dimensional coupled map lattices.

Stretched-exponential distributions and relaxation responses are encountered in a wide range of physical systems such as glasses, polymers, and spin glasses. As found recently, this type of behavior occurs also for the distribution function of a certain trap time in a number of coupled dynamical systems. We analyze a one-dimensional mathematical model of coupled chaotic oscillators that reproduces an experimental setup of coupled diode resonators and identify the necessary ingredients for stretched-exponential distributions.

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PubMed2001

Global optimization and the energy landscapes of Dzugutov clusters.

The global minima of clusters bound by a Dzugutov potential form non-compact polytetrahedral clusters mainly composed of interpenetrating and face-sharing 13-atom icosahedra. As the size increases, these icosahedral units first form linear arrays, then two-dimensional rings, then three-dimensional networks. Characterization of the energy landscapes of these clusters shows that they are particularly rough and generally exhibit a multiple-funnel topography. These results provide new insights into the structure and dynamics of bulk supercooled Dzugutov liquids and the form of the bulk phase diagram.

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