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S Tsonchev

Publications and source records attributed to S Tsonchev.

3 recordsLinked to original sources

Binary collision model for quantum brownian motion

A binary collision model for phenomena of quantum dissipation is developed. Unlike the harmonic oscillator model, widely used for over thirty years, this model assumes nonlinear coupling between system and environment, and is applicable to both bosonic and fermionic baths. The system interacts with an ideal bath through binary collisions only. Solutions for the classical and quantum-mechanical problems in the case of free Brownian motion are presented, and the quantum-classical correspondence for nonequilibrium processes is established. It is shown that in the Brownian motion limit the two models lead to identical dynamical behavior, provided the coupling coefficients in the harmonic oscillator Hamiltonian are temperature dependent. For cases of bath particles of finite mass and number the two models lead to different results. Linear response theory for the model is developed, and the results are compared with those for the harmonic oscillator model. At the end, possible applications of the model are suggested.

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Partitioning of a polymer chain between two confining cavities: the role of electrostatic interactions

A recently developed lattice field theory approach to the statistical mechanics of charged polymers in electrolyte solutions [S. Tsonchev, R. D. Coalson, and A. Duncan, Phys. Rev. E 60, 4257, (1999)] is generalized to the case where ground-state dominance in the polymer's Green's function does not apply. The full mean-field equations for the system are derived and are shown to possess a unique solution. The approach is applied to the problem of a charged Gaussian polymer chain confined to move within the region defined by two fused spheres. The failure of the notion of ground-state dominance under certain conditions even in the limit of large monomer number is demonstrated.

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Statistical mechanics of charged polymers in electrolyte solutions: a lattice field theory approach.

The lattice field theory approach to the statistical mechanics of a classical Coulomb gas [R.D. Coalson and A. Duncan, J. Chem. Phys. 97, 5653 (1992)] is generalized to include charged polymer chains. Saddle-point analysis is done on the functional integral representing the partition function of the full system. Mean-field level analysis requires extremization of a real-valued functional which possesses a single minimum, thus guaranteeing a unique solution. The full mean-field equations for such a coupled system are derived, as well as the leading (one-loop) fluctuation corrections. Two different numerical real-space lattice procedures are developed to implement the generalized theory; these are applied to the problem of a charged polymer confined to a spherical cavity in an electrolyte solution. The results provide insight into the physics of confined polyelectrolytes.

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