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SC Roy

Publications and source records attributed to SC Roy.

11 recordsLinked to original sources

Measurement of the viscosity of irradiated silicone using a differential viscometer

High-energy electron (2.0 MV) and gamma irradiation (60Co) has been used to modify polymeric silicone fluids of initial viscosities in the range, 90-700 cSt. Doses of electron and gamma radiation were delivered at rates of 0.246 kGy s(-1) and 15 kGy h(-1), respectively, exposure times being adjusted to ensure energy deposition in the range 30-360 kGy. Measurements were made using a differential viscometer based on a Bose Institute design. In line with expectation, samples of greater initial molecular weight (and hence greater viscosity), were observed to be more susceptible to radiation induced cross-linking than those of lower molecular weight. The role of dose rate and oxygen diffusion in determining the extent of change is discussed.

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How high can the temperature of a liquid be raised without boiling?

How high the temperature of a liquid can be raised beyond its boiling point without vaporizing (known as the limit of superheat) is an interesting subject of investigation. A different method of finding the limit of superheat of liquids is presented here. The superheated liquids are taken in the form of drops suspended in a dust free gel. The temperature of the superheated liquid is increased very slowly from room temperature to the temperature at which the liquid nucleates to boiling. The nucleation is detected acoustically by a sensitive piezoelectric transducer, coupled to a multichannel scaler, and the nucleation rate is observed as a function of time. The limit of superheat measured by the present method supersedes other measurements and theoretical predictions in reaching the temperature closest to the critical temperature of the liquids.

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