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Sergio Caracciolo

Publications and source records attributed to Sergio Caracciolo.

7 recordsLinked to original sources

Virial coefficients and osmotic pressure in polymer solutions in good-solvent conditions.

We determine the second, third, and fourth virial coefficients appearing in the density expansion of the osmotic pressure Pi of a monodisperse polymer solution in good-solvent conditions. Using the expected large-concentration behavior, we extrapolate the low-density expansion outside the dilute regime, obtaining the osmotic pressure for any concentration in the semidilute region. Comparison with field-theoretical predictions and experimental data shows that the obtained expression is quite accurate. The error is approximately 1%-2% below the overlap concentration and rises at most to 5%-10% in the limit of very large polymer concentrations.

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Polymer size in dilute solutions in the good-solvent regime.

We determine the density expansion of the radius of gyration, of the hydrodynamic radius, and of the end-to-end distance for a monodisperse polymer solution in good-solvent conditions. We consider the scaling limit (large degree of polymerization), including the leading scaling corrections. Using the expected large-concentration behavior, we extrapolate these low-density expansions outside the dilute regime, obtaining a prediction for the radii for any concentration in the semidilute region. For the radius of gyration, comparison with field-theoretical predictions shows that the relative error should be at most 5% in the limit of very large polymer concentrations.

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Critical behavior of the two-dimensional randomly driven lattice gas.

We investigate the critical behavior of the two-dimensional randomly driven lattice gas, in which particles are driven along one of the lattice axes by an infinite external field with randomly changing sign. A finite-size scaling (FSS) analysis provides novel evidences that this model is not in the same universality class as the driven lattice gas with a constant drive (DLG), contrarily to what has been recently reported in the literature. Indeed, the FSS functions of transverse observables (i.e., related to order-parameter fluctuations with wave vector perpendicular to the direction of the field) differ from the mean-field behavior--both predicted and observed in the DLG. In sharp contrast to the case of the DLG, FSS can be established only for rectangular lattices where the dimension in the direction of the field grows as the second power of the other dimension. Further, the transverse Binder cumulant does not vanish at the critical point.

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Fermionic field theory for trees and forests.

We prove a generalization of Kirchhoff's matrix-tree theorem in which a large class of combinatorial objects are represented by non-Gaussian Grassmann integrals. As a special case, we show that unrooted spanning forests, which arise as a q-->0 limit of the Potts model, can be represented by a Grassmann theory involving a Gaussian term and a particular bilocal four-fermion term. We show that this latter model can be mapped, to all orders in perturbation theory, onto the N-vector model at N=-1 or, equivalently, onto the sigma model taking values in the unit supersphere in R(1|2). It follows that, in two dimensions, this fermionic model is perturbatively asymptotically free.

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Two-dimensional Heisenberg model with nonlinear interactions.

We investigate a two-dimensional classical N-vector model with a nonlinear interaction (1+sigma(i) x sigma(j))(p) in the large-N limit. As observed for N=3 by Blöte et al. [Phys. Rev. Lett. 88, 047203 (2002)], we find a first-order transition for p>p(c) and no finite-temperature phase transitions for p p(c), both phases have short-range order, the correlation length showing a finite discontinuity at the transition. For p=p(c), there is a peculiar transition, where the spin-spin correlation length is finite while the energy-energy correlation length diverges.

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Dynamic critical behavior of an extended reptation dynamics for self-avoiding walks.

We consider lattice self-avoiding walks and discuss the dynamic critical behavior of two dynamics that use local and bilocal moves and generalize the usual reptation dynamics. We determine the integrated and exponential autocorrelation times for several observables, perform a dynamic finite-size scaling study of the autocorrelation functions, and compute the associated dynamic critical exponents z. For the variables that describe the size of the walks, in the absence of interactions we find z approximately 2.2 in two dimensions and z approximately 2.1 in three dimensions. At the theta point in two dimensions we have z approximately 2.3.

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