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T Uzer

Publications and source records attributed to T Uzer.

At least 19 recordsLinked to original sources
PubMed2001

Impenetrable barriers in phase-space.

Dynamical systems theory is used to construct a general phase-space version of transition state theory. Special multidimensional separatrices are found which act as impenetrable barriers in phase-space between reacting and nonreacting trajectories. The elusive momentum-dependent transition state between reactants and products is thereby characterized. A practical algorithm is presented and applied to a strongly coupled Hamiltonian.

Journal Article↗
PubMed2000

Transition state theory without time-reversal symmetry: chaotic ionization of the hydrogen atom

We present the first application of transition state theory to a system that evolves from an initial to a final state without time-reversal symmetry. The problem studied is the chaotic ionization of a hydrogen atom in crossed electric and magnetic fields. The stable manifolds of the transition state reveal a fractal tiling which connects the geometrical properties of the tiling to the ionization rate, leading to a theoretical explanation for the computational and experimental observation of "prompt" and "delayed" electrons in this problem.

Journal Article↗
PubMed2000

Stabilization of molecular atoms

We demonstrate the possibility of stabilizing the motion of ion-pair states through the use of external electric and magnetic fields. In conjunction with the Coulomb force, these fields can be engineered so as to lead to the creation of outer equilibrium points which can support non-spreading coherent wavepackets and long-lived states. Specific application is made to the H(+)-H- ion pair, recently investigated using threshold ion-pair production spectroscopy (TIPPS).

Journal Article↗