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Tahar Jouini

Publications and source records attributed to Tahar Jouini.

4 recordsLinked to original sources

[Li(MoO2)2O(AsO4)].

Single crystals of the molybdenum arsenate Li(MoO2)2O(AsO4) [lithium bis(dioxomolybdenum) arsenate oxide] have been prepared by solid-state reaction. The framework of Li(MoO2)2O(AsO4) consists of corner-shared Mo2AsO12 structural units, which form layers parallel to the ab plane. The Mo2AsO12 units result from the association of corner-shared AsO4 tetrahedra and Mo2O9 dimers. The Li+ ions are located between layers in a square-based-pyramidal environment. This structure is compared with those containing M2O9 dimers (M = Mo, Fe or V). The As, Li and one of the O atoms lie at sites with mm symmetry, while the Mo atom and two of the O atoms lie at sites with m symmetry.

English Abstract↗

[catena-Poly[[[(N,N,N',N'-tetramethylethylenediamine)copper(II)]-mu-oxalato] tetrahydrate]].

In the title compound, {[Cu(C2O4)(C6H16N2)].4H2O}n, the Cu atom is six-coordinate in a distorted octahedral geometry, and N,N,N',N'-tetramethylethylenediamine acts as a chelating ligand. The oxalate anion, which lies about an inversion centre, bridges the metal cations and forms infinite chains. The structure cohesion is ensured by hydrogen-bonding interactions, which form a three-dimensional framework.

English Abstract↗

AgNi3(PO4)(HPO4)2: an alluaudite-like structure.

The new title phosphate, silver trinickel phosphate bis(hydrogenphosphate), has been synthesized by the hydrothermal method. It has an alluaudite-like structure but shows some differences owing to the presence of the H atoms. The structure is isomorphous with the compounds of general formula AM(3)(XO(4))(HXO(4))(2) (A is Na or Ag, M is Co, Zn or Mn, and X is As or P), with the Ag atom, one Ni atom and one P atom lying on twofold axes.

Journal Article↗