Biomedical subjects

V Krakoviack

Publications and source records attributed to V Krakoviack.

3 recordsLinked to original sources

PubMed2005

Liquid-glass transition of a fluid confined in a disordered porous matrix: a mode-coupling theory.

We derive an extension of the mode-coupling theory for the liquid-glass transition to a class of models of confined fluids, where the fluid particles evolve in a disordered array of interaction sites. We find that the corresponding equations are similar to those describing the bulk, implying that the methods of investigation which were developed there are directly transferable to this new domain of application. We then compute the dynamical phase diagram of a simple model system and show that new and nontrivial transition scenarios, including reentrant glass transitions and higher-order singularities, can be predicted from the proposed theory.

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PubMed2003

Influence of solvent quality on effective pair potentials between polymers in solution.

Solutions of interacting linear polymers are mapped onto a system of "soft" spherical particles interacting via an effective pair potential. This coarse-graining reduces the individual monomer-level description to a problem involving only the center of mass (c.m.) of the polymer coils. The effective pair potentials are derived by inverting the c.m. pair distribution function, generated in Monte Carlo simulations, using the hypernetted chain closure. The method, previously devised for the self-avoiding walk model of polymers in good solvent, is extended to the case of polymers in solvents of variable quality by adding a finite nearest-neighbor monomer-monomer attraction to the previous model and varying the temperature. The resulting effective pair potential is found to depend strongly on temperature and polymer concentration. At low concentration the effective interaction becomes increasingly attractive as the temperature decreases, eventually violating thermodynamic stability criteria. However, as polymer concentration is increased at fixed temperature, the effective interaction reverts to mostly repulsive behavior. These issues help to illustrate some fundamental difficulties encountered when coarse-graining complex systems via effective pair potentials.

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PubMed2002

Langevin dynamics of the Coulomb frustrated ferromagnet: A mode-coupling analysis.

We study the Langevin dynamics of the soft-spin, continuum version of the Coulomb-frustrated Ising ferromagnet. By using the dynamical mode-coupling approximation, supplemented by reasonable approximations for describing the equilibrium static correlation function, and the somewhat improved dynamical self-consistent screening approximation, we find that the system displays a transition from an ergodic to a nonergodic behavior. This transition is similar to that obtained in the idealized mode-coupling theory of glass-forming liquids and in the mean-field generalized spin glasses with one-step replica symmetry breaking. The significance of this result and the relation to the appearance of a complex free-energy landscape are also discussed.

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