Biomedical subjects

V P Soprunyuk

Publications and source records attributed to V P Soprunyuk.

2 recordsLinked to original sources

PubMed2006

Structural transformations of even-numbered n-alkanes confined in mesopores.

The n-alkanes C12H26, C14H30, and C16H34 have been imbibed and solidified in mesoporous Vycor glass with a mean pore diameter of 10 nm. The samples have been investigated by x-ray diffractometry and calorimetric measurements. The structures and phase sequences have been determined. Apart from a reduction and the hysteresis of the melting-freezing transition, pore-confined C12 reproduces the liquid-triclinic phase sequence of the bulk material, but for C16 an orthorhombic rotator mesophase appears that in the bulk state is absent for C16 but well known from odd-numbered alkanes of similar length. In pore-confined C14 this phase shows up on cooling but not on heating.

Journal Article↗

PubMed2005

Faraday instability in a surface-frozen liquid.

Faraday surface instability measurements of the critical acceleration, a(c), and wave number, k(c), for standing surface waves on a tetracosanol (C24H50) melt exhibit abrupt changes at T(s)=54 degrees C, approximately 4 degrees C above the bulk freezing temperature. The measured variations of a(c) and k(c) vs temperature and driving frequency are accounted for quantitatively by a hydrodynamic model, revealing a change from a free-slip surface flow, generic for a free liquid surface (T>T(s)), to a surface-pinned, no-slip flow, characteristic of a flow near a wetted solid wall (T<T(s)). The change at T(s) is traced to the onset of surface freezing, where the steep velocity gradient in the surface-pinned flow significantly increases the viscous dissipation near the surface.

Journal Article↗