Biomedical subjects

W H de Jeu

Publications and source records attributed to W H de Jeu.

6 recordsLinked to original sources

PubMed2006

Main-chain smectic liquid-crystalline polymers as randomly disordered systems.

We report a high-resolution X-ray lineshape study of main-chain smectic polymers. The results indicate that the layer ordering differs fundamentally from the algebraic decay typical for other smectic liquid-crystalline systems. The lineshapes are best described by broad squared Lorentzians indicating some form of short-range correlations. However, several higher harmonics are observed, which excludes simple liquid-like short-range order. This behaviour is tentatively attributed to a random field of defects associated with entangled hairpins in the main-chain polymer structure.

Complex Mixtures↗

PubMed2004

Thickening of a smectic membrane in an evanescent X-ray beam.

We report an unusual thickening of smectic membranes under the influence of X-ray irradiation below the critical angle. In the case of a four-layer film the thickness was found to grow at the footprint of the beam, reaching within minutes tens of layers. The effect is attributed to the localized energy dissipation of the evanescent wave. The "island" thus created is not connected to the meniscus and after the beam is switched off the film returns to its original state. A possible explanation is given in terms of a local disrupture of the tension of the smectic membrane.

Membranes, Artificial↗

PubMed2002

How do smectic liquid crystals of different molecular length mix in thin films?

We present a model for the structure of binary mixtures of smectic compounds in freely suspended films of 2-7 layers. The compounds are the hexyl (6AB) and dodecyl (10AB) homologues of p, p'-dialkylazoxybenzene that differ by about 40% in molecular length. X-ray reflectivity indicates that no demixing occurs between 6AB and 10AB molecules, while also there is no indication found of increased roughness at the film surfaces. However, the surface layers are somewhat expanded compared to the interior layers. This can be explained by backfolding of the dodecyl end chains of 10AB molecules at the surface via two gauche kinks, which ensures dense packing. This model is supported by surface tension measurements that indicate an increased amount of alkyl groups at the surfaces.

Journal Article↗

PubMed2001

Structure of freely suspended chiral smectic films as determined by x-ray reflectivity and optical ellipsometry.

We report on a combined x-ray reflectivity and optical ellipsometry study of freely suspended smectic (Sm) films of a chiral liquid crystalline compound with the phase sequence Sm-A-Sm-C(*)(alpha)-Sm-C*-Sm-C(*)(gamma)-Sm-C(*)(A). Using tilt magnitude profiles from x-ray reflectivity as input to model the average optical properties obtained by ellipsometry, tilt direction profiles are also obtained. In this way realistic models can be elaborated for the various types of chiral Sm-C films. We find that the surface layers are more tilted than the interior layers due to surface interactions and finite size effects. For the ferrielectric Sm-C(*)(gamma) phase the tilt direction profile corresponds to a three-layer helix, in agreement with the clock model of chiral Sm-C phases. In thin films the surface interactions suppress the bulk helix structure of the Sm-C(*)(alpha) phase and a Sm-C(*)(A)-like structure is formed with an anticlinic layer-by-layer alternation of the tilt directions.

Journal Article↗

PubMed2001

Crystalline smectic-B films as fluctuating systems: static and dynamic x-ray scattering.

Static and dynamic x-ray scattering has been used to characterize thermal fluctuations in free-standing smectic films in the crystalline-B phase. The results are remarkably similar to those in smectic-A films, in spite of the three-dimensional positional order in the crystalline-B phase. The main difference is the disappearance of the characteristic Landau-Peierls instability of the smectic-A phase. The dynamic nature of the fluctuations is explicitly demonstrated by x-ray photon correlation spectroscopy. This fluctuation behavior of crystalline-B films can be attributed to the small value of the shear elastic constant C44.

Journal Article↗

PubMed1999

Layer-by-layer crystallization and the role of fluctuations in free standing smectic films.

Specular x-ray reflectivity has been used to study the changes in the thermal fluctuation behavior of eight layer freely suspended N-(4-n-butoxybenzilidene)-4-n-octylaniline (4O.8) films during the process of successive layer-by-layer crystallizations. Each of these steps is preceded by the formation of an intermediate layer structure with in-plane hexatic ordering. We find an unusually large reduction of the fluctuations after the emergence of only the first hexatic toplayer. The fluctuation profiles over the film are in all cases quenched at the surfaces though less so after each crystallization step. This behavior supports theoretical arguments that hexatic order is reduced by out-of-plane smectic layer fluctuations.

Journal Article↗