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W Zhijian

Publications and source records attributed to W Zhijian.

2 recordsLinked to original sources

Physicochemical Studies of the Sea Surface Microlayer.

The sea surface microlayer and its thickness are theoretically analyzed. A multiple-layer model of the sea surface microlayer is proposed. Through in situ and laboratory imitation experiments using glass plate, rotating drum, screen, and funnel samplers, the relationships between pH, surface tension, the concentrations of dissolved trace metals Cu and Pb, phosphate, and particulate and sampling thicknesses are carefully investigated. The apparent sampling thickness of the sea surface microlayer is determined to be 50 +/- 10 µm, which is basically consistent with the mean thickness of the liquid boundary film in the models of gas exchange across the sea surface. Copyright 1998 Academic Press.

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Studies of Ternary Surface Complexes at Liquid-Solid Interfaces in Seawater

The E (%)-pH curves of the ternary surface complexes at liquid-solid interfaces in the simulated seawater system of alpha-FeOOH-Cu(II)-tryptophan were determined. The diffuse reflectance IR spectra of the species at the solid surfaces in the above ternary equilibration system were examined. The above two results were comparatively studied. It is shown that the coadsorption of Cu(II) and tryptophan on alpha-FeOOH surface results in the formation of the ternary surface complex. Cu(II) can promote the exchange adsorption of tryptophan on alpha-FeOOH surface. The diffuse reflectance IR spectra can give us some evidence for the structure of the ternary surface complex, and these results are in accordance with the results of the E (%)-pH curves.

Journal Article↗