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X Urbain

Publications and source records attributed to X Urbain.

6 recordsLinked to original sources

Reactive collisions between CH+ and O-.

Integral cross sections were measured for two reactions occurring in CH+ + O- collisions: the formation of the carbon monoxide cation CO+ via a reactive ionization process and the formation of the (iso)formyl cation HCO+ (HOC+) via the associative ionization process. Both carbon monoxide and formyl cations are present in the interstellar medium, the latter one being quite abundant in dense clouds. Provided the oxygen anion would also be present in the interstellar environment, the large efficiency of the two reactive processes reported here would justify their inclusion in astrochemical models. The whole set of data was obtained by means of a merged-beam setup operating with keV beams.

Journal Article↗

Intense-laser-field ionization of molecular hydrogen in the tunneling regime and its effect on the vibrational excitation of H2+.

H2 molecules were ionized by Ti:sapphire (45 fs, 800 nm) and Nd-doped yttrium aluminum garnet lasers (6 ns, 1064 nm). The relative populations of the vibrational levels of the H+2 ions were determined and found to be concentrated in the lowest vibrational levels. Tunneling ionization calculations with exact field-modified potential curves reproduce the experimental results. The reason for the departure from conventional Franck-Condon-like distributions is the rapid variation of the ionization rate with internuclear distance.

Journal Article↗