Absorption Intensity of Stretching Overtone States of Silane and Germane.
The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1-5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived by linear least-squares fitting. The relative intensities of overtones can be satisfactorily reproduced with the bond dipole model containing two adjustable parameters. Copyright 1998 Academic Press.