Biomedical subjects

Xiangjun Xing

Publications and source records attributed to Xiangjun Xing.

5 recordsLinked to original sources

PubMed2005

Phases and transitions in phantom nematic elastomer membranes.

Motivated by recently discovered unusual properties of bulk nematic elastomers, we study a phase diagram of liquid-crystalline polymerized phantom membranes, focusing on in-plane nematic order. We predict that such membranes should generically exhibit five phases, distinguished by their conformational and in-plane orientational properties: namely, isotropic-crumpled, nematic-crumpled, isotropic-flat, nematic-flat, and nematic-tubule phases. In the nematic-tubule phase, the membrane is extended along the direction of spontaneous nematic order and is crumpled in the other. The associated spontaneous symmetries breaking guarantees that the nematic tubule is characterized by a conformational-orientational soft (Goldstone) mode and the concomitant vanishing of the in-plane shear modulus. We show that long-range orientational order of the nematic tubule is maintained even in the presence of harmonic thermal fluctuations. However, it is likely that tubule's elastic properties are qualitatively modified by these fluctuations, which can be studied using a nonlinear elastic theory for the nematic tubule phase that we derive at the end of this paper.

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PubMed2004

Scaling of entropic shear rigidity.

The scaling of shear modulus near the gelation-vulcanization transition is explored heuristically and analytically. It is found that in a dense melt the effective chains of the infinite cluster have sizes that scale sublinearly with their contour length. Consequently, each chain contributes k(B)T to the rigidity, which leads to a shear-modulus exponent dnu. In contrast, in phantom elastic networks the scaling is linear in the contour length, yielding an exponent identical to that of the random resistor network conductivity, as predicted by de Gennes. For nondense systems, the exponent should cross over to dnu when the percolation correlation length is much larger than the density-fluctuation length.

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PubMed2003

Fluctuating nematic elastomer membranes.

We study the flat phase of nematic elastomer membranes with rotational symmetry spontaneously broken by an in-plane nematic order. Such a state is characterized by a vanishing elastic modulus for simple shear and soft transverse phonons. At harmonic level, the in-plane orientational (nematic) order is stable to thermal fluctuations that lead to short-range in-plane translational (phonon) correlations. To treat thermal fluctuations and relevant elastic nonlinearities, we introduce two generalizations of two-dimensional membranes in a three-dimensional space to arbitrary D-dimensional membranes embedded in a d-dimensional space and analyze their anomalous elasticities in an expansion about D=4. We find a stable fixed point that controls long-scale properties of nematic elastomer membranes. It is characterized by singular in-plane elastic moduli that vanish as a power law eta(lambda)=4-D of a relevant inverse length scale (e.g., wave vector) and a finite bending rigidity. Our predictions are asymptotically exact near four dimensions.

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PubMed2003

Universal elasticity and fluctuations of nematic gels.

We study elasticity of spontaneously orientationally ordered amorphous solids, characterized by a vanishing transverse shear modulus, as realized by nematic elastomers and gels. We show that local heterogeneities and elastic nonlinearities conspire to lead to anomalous nonlocal universal elasticity controlled by a nontrivial infrared fixed point. Namely, such solids are characterized by universal shear and bending moduli that, respectively, vanish and diverge at long scales, are universally incompressible, and exhibit a universal negative Poisson ratio and a non-Hookean elasticity down to arbitrarily low strains. Based on expansion about five dimensions, we argue that the nematic order is stable to thermal fluctuation and local heterogeneities down to d(lc)<3.

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PubMed2002

Symmetries and elasticity of nematic gels.

A nematic liquid-crystal gel is a macroscopically homogeneous elastic medium with the rotational symmetry of a nematic liquid crystal. In this paper, we develop a general approach to the study of these gels that incorporates all underlying symmetries. After reviewing traditional elasticity and clarifying the role of broken rotational symmetries in both the reference space of points in the undistorted medium and the target space into which these points are mapped, we explore the unusual properties of nematic gels from a number of perspectives. We show how symmetries of nematic gels formed via spontaneous symmetry breaking from an isotropic gel enforce soft elastic response characterized by the vanishing of a shear modulus and the vanishing of stress up to a critical value of strain along certain directions. We also study the phase transition from isotropic to nematic gels. In addition to being fully consistent with approaches to nematic gels based on rubber elasticity, our description has the important advantages of being independent of a microscopic model, of emphasizing and clarifying the role of broken symmetries in determining elastic response, and of permitting easy incorporation of spatial variations, thermal fluctuations, and gel heterogeneity, thereby allowing a full statistical-mechanical treatment of these materials.

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