Biomedical subjects

Xiaoyang Chen

Publications and source records attributed to Xiaoyang Chen.

2 recordsLinked to original sources

PubMed2006

Kinetics of oxidative decolorization and mineralization of Acid Orange 7 by dark and photoassisted Co2+-catalyzed peroxymonosulfate system.

A kinetic model was proposed and used to interpret the experimental data for degradation of Acid Orange 7 (AO7) in aqueous solution induced by Co(2+)/peroxymonosulfate (Co/PMS) reagent in terms of both decolorization and mineralization. The pseudo first-order decolorization rate constants are related to [Co(2+)], [PMS], reciprocal of [H(+)] and [AO7](0). Activation energy of the AO7 decolorization process was determined to be 75.7 kJ mol(-1). UV and visible light can accelerate the decolorization and mineralization process due to different mechanisms. In the combined UV/Co/PMS system, UV light can decompose PMS to generate hydroxyl ((*)OH) and sulfate radicals (SO(4)(*-)), while in the Vis/Co/PMS system, excited AO7 molecules can transfer electrons to PMS or Co(3+) and thus accelerate the decomposition of PMS and catalytic cycle of Co(3+)/Co(2+).

Azo Compounds↗

PubMed2005

Quantitative relationships between molecular structures, environmental temperatures and solid vapor pressures of PCDD/Fs.

Based on quantum chemical and topological descriptors, temperature-dependent predictive models for solid vapor pressure (PS) of PCDD/Fs were developed. The inclusion of the two topological descriptors, Kier symmetry index (S0K) and Kier flexibility index (PHI), as predictor variables, improved the statistical significance of models. Thus the entropic factors described by the two topological descriptors play a role in influencing the PS values. The cumulative variance of the dependent variable explained by the PLS components and determined by cross-validation (Qcum2), for the final model, is 0.972, indicating that the model has good predictive ability and robustness, and could be used to estimate PS values of PCDD/Fs at different temperatures. The main factors governing log PS values of PCDD/Fs, from important to less important, are temperature, intermolecular dispersive interactions, entropic factor, and intermolecular dipole-dipole and dipole-induced dipole interactions.

Benzofurans↗