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Y Hemar

Publications and source records attributed to Y Hemar.

4 recordsLinked to original sources

DWS microrheology of a linear polysaccharide.

Diffusing wave spectroscopy has been used to measure the rheological behavior of pullulan (M(w) = 1 x 10(5)) aqueous solutions up to concentration of 40 g/dL. It was found that these solutions were mainly viscous, with the loss modulus G'' higher than the elastic modulus G'. The plot of the specific viscosity eta(sp) as a function of pullulan concentration showed two critical concentrations c = 4 g/dL and c = 15 g/dL. For c < c, eta( sp) approximately c(1.25+/-0.05); for c < c < c, eta( sp) approximately c(2+/-0.05); and for c > c, eta( sp) approximately c(4.5+/-0.5). These results are in very good agreement with those reported in the literature.

Biopolymers↗

Monitoring of flocculation and creaming of sodium-caseinate-stabilized emulsions using diffusing-wave spectroscopy.

Diffusing-wave spectroscopy (DWS) has been used to study the stability of sodium-caseinate-stabilized emulsions. The emulsions underwent creaming as a result of depletion flocculation when excess sodium caseinate was added. The creaming process was monitored over a 3-h period and each autocorrelation function was collected for 2 min to ensure adequate signal-to-noise ratio. The temporal variation of average particle size times the coefficient of viscosity of the continuous phase was derived from the backscattering measurements, and the variation of the scattering mean free path length with time was found from the backscattering and transmission measurements. It was confirmed that the creaming process was delayed at high oil concentrations, presumably due to the formation of oil droplet networks.

Journal Article↗

Dynamic light scattering investigation of sodium caseinate and xanthan mixtures.

Aqueous solutions of sodium caseinate and xanthan at pH 7 and containing 0.1 M NaCl, and their mixtures were investigated using dynamic light scattering. Sodium caseinate solutions showed a bimodal distribution of relaxation rates; with the aggregate peak distribution predominating. Xanthan solutions showed a single distribution at low concentrations (< or =0.06 wt.%) and a bimodal distribution at higher concentrations. The sodium caseinate-xanthan mixture modes were independent of the total biopolymer concentration, and behaved as a superposition of sodium caseinate solution alone and xanthan solution alone. This indicates that there is no interaction between xanthan and sodium caseinate in the range of concentrations considered in this study.

Caseins↗

Electrostatic Interactions in Adsorbed Protein Layers Probed by a Sedimentation Technique.

A simple centrifugation technique has been used to determine the thicknesses of layers of alphaS1-casein and beta-casein adsorbed onto monodisperse polystyrene latex particles. The influence of electrostatic interactions within the layers on their thickness and stabilizing ability is investigated by varying the ionic strength of the suspension or by including calcium ions, known to bind specifically to the caseins. Copyright 1998 Academic Press.

Journal Article↗