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Zhen-bo Deng

Publications and source records attributed to Zhen-bo Deng.

5 recordsLinked to original sources

[Luminescence properties of rare earth complexes Tb(BSA)4].

A new rare earth complex Tb(BSA)4 was synthesized and studied. Pure green and narrow band emission was generated from the device with structure ITO/PVK:Tb(BSA)4 /Alq3 /LiF/Al, where PVK was used to improve the film-formation and hole-transport property of the Tb(BSA)4. The absorption mechanism, and the photoluminescence and electroluminescence mechanisms are discussed. It has been proved that there exists energy transfer from PVK to Tb(BSA)4 and the mechanisms of photoluminescence and electroluminescence are different. The effect of different ratios of PVK on the device characteristics is also studied.

Luminescence↗

[Electroluminescent device based on rare earth terbium complex].

Rare earth complex TbY(m-MBA)6 (phen)2.2H20 have been synthesized, which were used as emitting materials in electroluminescence. Single-layer devices and bilayer devices with Alq as electron transmission layer have been fabricated. The electroluminescent properties of the devices were studied. The electroluminescent mechanism of the devices was proposed by measuring and analyzing the emission and the excitation spectra of the emissive layer. Y3+ may play the role to promote the energy transfer from ligand to Tb3+ and the possible energy transfer process of the device was preliminarily discussed.

Electrochemical Techniques↗

[Electroluminescent device based on terbium complex].

Rare earth complex Tb(BA)3phen has been synthesized, which is used as an emitting material in electroluminescence. The properties of monolayer device with the rate of 1000 r x min(-1) and the impure concentration of 1:5 are the best. And the highest brightness of this device reached 26.8 cd x cm(-2) at a fixed bias of 21 V. Bright green emission can be obtained from the optimized double-layer device and the highest EL brightness of the device reaches 322cd x m(-2) at the voltage of 22 V.

English Abstract↗

[The luminescence characteristic of a new novel coprecipitate rare earths complexes].

A new novel coprecipitate rare earths complexes La0.6Eu0.4(BSA)3phen has been synthesized and was chosen as the emitter material in the organic electroluminescent devices: ITO/PVK: La0.6Eu0.4(BSA)3phen/Alq/Al where PVK was used to improve the film-forming and hole-transporting property of the La0.6Eu0.4(BSA)3phen. It has been proved that it exists Förster energy transfer process from La3+ to Eu3+. This device has also been compared with the devices: ITO/PVK: Eu(BSA)3phen/Alq/Al and ITO/PVK: Tb0.6Eu0.4(BSA)3phen/Alq/Al. From the data, it indicated the device has the good purity of red color and good commutation property. The maximum EL brightness of 102 cd x m(-2) had been got.

English Abstract↗

[Emission mechanism in the Tb complex doped PVK system].

Excitation and photoluminescence (PL) spectra of the mixture terbium complex and PVK were investigated. The excitation spectrum of Tb complex dispersed PVK film is very similar to that of the pure PVK film, indicting that energy transfer occurs from PVK to Tb complex. For the overlap between the excitation spectrum of Tb complex dispersed PVK film and the PL spectrum of PVK film is very little, the ratio of occurrence for Förester energy transfer is very little. The emission of Tb3+ mainly comes from the excited ligand, which comes from the ligand capture of electron-hole pairs. In the electroluminescence (EL) spectra, the emission of PVK is completely restrained and only emission of Tb3+ is occured, which origins from the different mechanism in comparison with photoluminescence.

Europium↗