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Zhi-Gang Shao

Publications and source records attributed to Zhi-Gang Shao.

3 recordsLinked to original sources

PtRu/Ti anodes with varying Pt ratio: Ru ratio prepared by electrodeposition for the direct methanol fuel cell.

PtRu/Ti anodes with varying Pt ratio Ru ratio were prepared by electrodeposition of a thin PtRu catalyst layer onto Ti mesh for a direct methanol fuel cell (DMFC). The morphology and structure of the catalyst layers were analyzed by SEM, EDX and XRD. The catalyst coating layer shows an alloy character. The relative activities of the PtRu/Ti electrodes were assessed and compared in half cell and single DMFC experiments. The results show that these electrodes are very active for the methanol oxidation and that the optimum Ru surface coverage was ca. 9 at.% for DMFC operating at 20 degrees C and 11 at.% at 60 degrees C. The PtRu/Ti anode shows a performance comparable to that of the conventional carbon-based anode in a DMFC operating with 0.25 M or 0.5 M methanol solution and atmosphere oxygen gas at 90 degrees C.

Electric Power Supplies↗

Particle-cluster aggregation on a small-world network.

To describe the aggregation behaviors on substrates with long-range jump paths, a model of particle-cluster aggregation on a two-dimensional small-world network is presented. This model is characterized by two parameters: the clustering exponent alpha and the long-range connection rate phi. The results show that there exists an asymptotic fractal dimension D(max)(f) that depends upon alpha. With decrement of alpha, D(max)(f) varies from 1.7 to 2.0, which corresponds to a crossover from diffusion-limited-aggregation-like to dense growth. The change of the aggregation pattern results from the long-range connection in the network, which reduces the effect of screening during the aggregation. When the system size is not large enough, the effective fractal dimension D(f) depends upon phi because of the finite-size effect. With primitive analysis, we obtain the expression of the effective fractal dimension D(f) with the network parameters alpha and phi.

Journal Article↗

Critical behavior of efficiency dynamics in small-world networks.

Some dynamical processes in a small-world network shows a critical transition at a finite disorder phi(c) of the network, in contrast with the geometrical properties that exhibit the critical behavior at phi(c)=0. Although it has been pointed out in previous works that the transition is related to the structural properties of the network, it is still not very clear why the transition occurs at phi(c) not equal 0. In this paper we present a simple social model of efficiency dynamics in small-world networks, which also shows a transition at phi(c)>0. We obtain the critical point with phi(c) approximately equal 0.098 from the finite-size analysis. It is found that both the geometrical properties of the network and the specific dynamical characters of the model contribute to the critical transition. This work is useful for understanding this kind of transition occurring in many dynamical processes in small-world networks.

Journal Article↗