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PubMed · 10205053

Single-crystal-like diffraction data from polycrystalline materials

Abstract

A method for solving structures from powder diffraction data was developed, and its validity was demonstrated on three complex structures. The method uses a textured sample and exploits the high intensity and parallel nature of synchrotron radiation. In principle, crystal structures as complex as those routinely solved by single-crystal methods can be determined with this approach. For example, the as-synthesized form of the zeolite UTD-1, with 69 nonhydrogen atoms in the asymmetric unit, could be solved directly. With this method, a larger range of structural complexity becomes accessible to scientists interested in the structures of polycrystalline materials that cannot be grown as single crystals.

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BibTeXRIS

T Wessels, C Baerlocher, LB McCusker. 1999-04-16. Single-crystal-like diffraction data from polycrystalline materials. https://doi.org/10.1126/science.284.5413.477

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