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Bond-valence parameters for ammonium-anion interactions.

L García-Rodríguez·A Rute-Pérez·J R Piñero·C González-Silgo
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Abstract

Bond-valence parameters r0 and b, relating bond valence and bond length, are calculated for interactions between the ammonium ion and anions X = O, F, Cl. Searches in the Cambridge Structural Database (CSD) and in the Inorganic Crystal Structural Database (ICSD) were performed to obtain the lengths of NH4+...X contacts for ammonium ion environments in different structures. The procedure, which represents an extension of previous methods, allows certain environments to be rejected and enables the calculation of r0 and b from a reasonable range of interaction distances. Results are in very good agreement with the expected values on the basis of the assumed bond-valence model and their overall applicability to ammonium ion interactions is discussed.

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AnionsDatabases as TopicModels, ChemicalMolecular StructureQuaternary Ammonium CompoundsJournal ArticleResearch Support, Non-U.S. Gov't

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L García-Rodríguez, A Rute-Pérez, J R Piñero, C González-Silgo. 2000. Bond-valence parameters for ammonium-anion interactions.. https://doi.org/10.1107/s0108768100002615

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