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Synchronized adiabatic decoupling.

S Zhang·D G Gorenstein
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Abstract

A new decoupling scheme termed "synchronized adiabatic decoupling" is developed for use in the indirectly detected dimension. After each increment, the decoupling sequence is replaced by another one with different period T or different initial period T(ini) so that sampling always occurs at the end of a complete decoupling period. The effects of J coupling are therefore completely averaged out for all data points. As a result, all decoupling sidebands disappear and the center band increases correspondingly. Since the synchronized adiabatic decoupling does not require conventional editing techniques to cancel the sidebands, it is useful in high-field gradient-enhanced multidimensional experiments with only a single scan per increment.

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AlgorithmsChemical PhenomenaChemistry, PhysicalGlycineMagnetic Resonance SpectroscopyJournal ArticleResearch Support, Non-U.S. Gov'tResearch Support, U.S. Gov't, P.H.S.

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BibTeXRIS

S Zhang, D G Gorenstein. 2000. Synchronized adiabatic decoupling.. https://doi.org/10.1006/jmre.2000.2183

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