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Fundamental differences between micro- and nano-Raman spectroscopy.

Abstract

Electric field polarization orientations and gradients close to near-field scanning optical microscope (NSOM) probes render nano-Raman fundamentally different from micro-Raman spectroscopy. With x-polarized light incident through an NSOM aperture, transmitted light has x, y and z components allowing nano-Raman investigators to probe a variety of polarization configurations. In addition, the strong field gradients in the near-field of a NSOM probe lead to a breakdown of the assumption of micro-Raman spectroscopy that the field is constant over molecular dimensions. Thus, for nano-Raman spectroscopy with an NSOM, selection rules allow for the detection of active modes with intensity dependent on the field gradient. These modes can have similar activity as infra-red absorption modes. The mechanism can also explain the origin and intensity of some Raman modes observed in surface enhanced Raman spectroscopy.

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BibTeXRIS

E J Ayars, C L Jahncke, M A Paesler, H D Hallen. 2001. Fundamental differences between micro- and nano-Raman spectroscopy.. https://doi.org/10.1046/j.1365-2818.2001.00878.x

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