PubMed · 11511271
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D F Taber, T E Christos, M Rahimizadeh, B Chen. 2001-08-24. A convenient chiron for substituted cyclohexanones.. https://doi.org/10.1021/jo001104v
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We report experimental results on the dynamics of excitation waves in a modified Belousov-Zhabotinsky reaction. The waves in this system obey nonmonotonic dispersion relations. This anomaly induces the stacking of excitation fronts into patterns with stable interpulse distances. The stacking process creates either a traveling shock structure or a cascade of bunching events in which metastable wave packets are formed. The direction and the speed of the shock are explained in terms of a simple geometrical analysis. We also present experimental evidence for the corresponding instabilities in two-dimensional systems. Here, wave stacking generates atypical structures in the collision of target patterns and wave bunching is accompanied by complex front deformations.
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[reaction: see text]. The synthesis of 2-phenyl-2,5-cyclohexadien-1-ones 1a-c and 2a-b from methyl 3-phenylbenzoate 4 and methyl 2-methoxy-5-phenylbenzoate 8 by the Birch reduction alkylation methodology is described. 1a-c and 2a-b undergo regiospecific photorearrangements at 300 nm to give tetrasubstituted phenols 14a-c and pentasubstituted phenols 18a-b, respectively. The type A photoproducts 17a-b resulting from irradiation of 2a-b at 366 nm have been isolated as approximately 1:1 diastereomer mixtures. When an optimized condition is applied, a single diastereomer of 17a is obtained.