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Characterisation of heterogeneous solid surfaces by multiple probe, temperature-programmed inverse gas chromatography (IGC). A feasibility study.

Abstract

A method is described for the characterisation of the surfaces of powdered solids by temperature programmed, multiple-probe, inverse gas chromatography. This modification of "traditional" inverse gas chromatography (IGC) allows rapid screening of solid surfaces to compare the adsorptive behaviour of pairs or sets of surfaces. This feasibility study examined the criteria for selection of a suitable probe set and approaches to the analysis and interpretation of the data generated. The technique was used to compare carbon black samples, chosen for their surface heterogeneity and the difficulty of surface characterisation using other techniques. The choice of a low surface area, methylated silica solid diluent and the elimination of its influence on the measurements is discussed. The probe set selected readily distinguished the carbon black samples and allowed tentative conclusions to be drawn regarding steric and electronic influences on probe-solid interactions.

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BibTeXRIS

Adam W McMahon, David G Kelly, Paul J McLaughlin. 2002. Characterisation of heterogeneous solid surfaces by multiple probe, temperature-programmed inverse gas chromatography (IGC). A feasibility study.. https://doi.org/10.1039/b104548m

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