Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex.

Keith Smith; Chia-Hui Liu

doi:10.1039/b200246a

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Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex.

Keith Smith·Chia-Hui Liu

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Abstract

We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a single hydroxyalkyl group at its 6-position, and also its Mn(III) complex; attachment of the complex to a polymer gives a highly enantioselective and recoverable catalyst for epoxidation of 1,2-dihydronaphthalene.

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Ethylenediamines Models, Chemical Naphthalenes Organometallic Compounds Oxidation-Reduction Polymers Solvents Stereoisomerism Journal Article

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Keith Smith, Chia-Hui Liu. 2002-04-21. Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex.. https://doi.org/10.1039/b200246a

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