PubMed Health⌕ Search

PubMed · 12201686

Utilisation of bottom ash in road construction: a lysimeter study.

Abstract

The incineration of municipal solid waste (MSW) results in the annual production of 2.7 million tons of bottom ash in France. Utilisation of bottom ash in road construction is encouraged in France but strictly regulated. Because the incinerator residues contain enriched concentrations of metals and salts, particular attention must be focused on the potential environmental problems. In the present study, a laboratory tool (lysimeter) has been developed to reproduce the conditions of bottom ash utilisation and to study their environmental impact via the percolates collected at the bottom of the lysimeter. Four lysimeter experiments were conducted in order to study reproducibility, as well as the influence of water flow rate and pressure on the composition of the percolates. The lysimeter experiments have been then compared with the utilisation of bottom ash under real conditions (two experimental road sections). The comparison of results of lysimeter test and those measured after performing the French standard leach test (AFNOR NF X31-210) shows a recovery of 89% for the chlorides and between 30 and 35% for the sulfates. This indicates that almost all chlorides have been dissolved, contrary to the sulfates, which are less soluble.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

V Bruder-Hubscher, F Lagarde, M J Leroy, C Coughanowr, F Enguehard. 2001. Utilisation of bottom ash in road construction: a lysimeter study.. https://doi.org/10.1177/0734242x0101900612

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related citations

Binding geometry and photophysical properties of DNA-threading binuclear ruthenium complexes.

The DNA binding conformation and the photophysical properties of the semiflexible binuclear ruthenium complex [micro-bidppz(phen)4Ru2]4+ (2) were studied with optical spectroscopy and compared to the rigid, planar homologue in syn conformation [micro-dtpf(phen)4Ru2]4+ (3) and the parent "light-switch" complex [Ru(phen)2dppz]2+ (1). Comparison of calculated and observed absorption bands of the bridging ligand, bidppz, confirm earlier suggestions that 2 is significantly nonplanar, both free in solution and when intercalated into poly(dAdT)2, but the conclusion that the intercalated conformation is an anti rotamer is not substantiated by comparison of linear and circular dichroism spectra of 2 and 3. The behavior of the emission quantum yield as a function of temperature is similar for the two binuclear complexes 2 and 3 in different protic solvents, and a quantitative analysis suggests that, in solution, the solvent is more strongly hydrogen bonded to the excited state of 2 than to 1. However, the observation that for 2 the radiative rate constant increases to a value similar to 1 upon intercalation into DNA suggests that the difference between 1 and 2 in accepting hydrogen bonds is less pronounced when intercalated.

Chlorides↗

Current status of the role of Cl(-) ion in the oxygen-evolving complex.

This minireview summarizes the current state of knowledge concerning the role of Cl(-) in the oxygen-evolving complex (OEC) of photosystem II (PSII). The model that proposes that Cl(-) is a Mn ligand is discussed in light of more recent work. Studies of Cl(-) specificity, stoichiometry, kinetics, and retention by extrinsic polypeptides are discussed, as are the results that fail to detect Cl(-) ligation to Mn and results that show a lack of a requirement for Cl(-) in PSII-catalyzed H(2)O oxidation. Mutagenesis experiments in cyanobacteria and higher plants that produce evidence for a correlation between Cl(-) retention and stable interactions among intrinsic and extrinsic polypeptides are summarized, and spectroscopic data on the interaction between PSII and Cl(-) are discussed. Lastly, the question of the site of Cl(-) action in PSII is discussed in connection with the current crystal structures of the enzyme.

Chlorides↗

N1303K and IVS8-5T, clinical presentation within a family with atypical cystic fibrosis.

The CFTR genotype N1303K/IVS8-5T can cause very mild cystic fibrosis (CF) and congenital bilateral absence of the vas deferens (CBAVD). We report one family consisting of five affected patients in two generations, presenting minor symptoms of CF at different ages, segregating the CFTR mutations N1303K and IVS8-T5-TG13 in trans. Common features were chronic sinopulmonary symptoms and borderline or slightly elevated sweat chloride values. One patient had CBAVD.

Chlorides↗